Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur
Patent
1991-03-25
1993-02-09
Breneman, R. Bruce
Chemistry of inorganic compounds
Sulfur or compound thereof
Elemental sulfur
422171, 422172, 422173, 422190, C01B 1704
Patent
active
051851407
ABSTRACT:
Process for removing sulphur-containing compounds from a residual gas with recovery of said compounds in the form of sulphur, wherein the residual gas is subjected to a treatment comprising a hydrogenation and a hydrolysis phase to provide the sulphur-containing compounds in the unique form of H.sub.2 S, a cooling step with water condensation, a catalytic oxidation of H.sub.2 S in CLAUS stoechiometry and a catalytic CLAUS reaction phase with deposition of sulphur on the CLAUS catalyst and periodic regeneration of the sulphur-laden catalyst and cooling of the regenerated catalyst. The gas used for the regeneration and for the cooling is tapped from the gas effluent supplied to the catalytic oxidation and the gas issued from the regeneration is reintroduced at least in part into said gas effluent after separation of the sulphur containing therein. Application to the purification of residual gases issued from CLAUS sulphur units.
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Kvasnikoff Georges
Nougayrede Jean
Philippe Andre
Breneman R. Bruce
Elf Aquitaine Production
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