Process for making cosmetic compositions using polyether...

Details Process for making cosmetic compositions using polyether... Process for making cosmetic compositions using polyether...

2003-03-21

2004-07-06

Moore, Margaret G. (Department: 1712)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

At least one aryl ring which is part of a fused or bridged...

C528S027000, C528S031000, C524S379000

Reexamination Certificate

active

06759479

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a method for making silicone compositions, more particularly to compositions comprising a silicone polymer network comprising cross-links derived from epoxide or oxirane moieites.
BACKGROUND OF THE INVENTION
The personal care industry thrives on being able to deliver multiple performance products based on mixtures of several components, with each having performance characteristics important to or desirable in the final formulation. One desirable characteristic is the ability to provide a silky initial feel derived from low molecular weight silicones, such as for example, octamethylcyclotetrasilioxane or decamethylcyclopentasiloxane, in the formulation while maintaining a high, but shear-thinnable viscosity. While these low molecular weight silicones provide the desired feel characteristics, they are also low viscosity, highly flowable liquids. Thus they are not easily held in a formulation, preferring rather to separate and flow out of a given container or flow uncontrollably across the skin when used in a specific application. Further, it desirable to achieve an initial silky feel while providing a smooth, low-residue feel upon dry-down. Polymeric silicone gels prepared in volatile silicone have been found to deliver desirable initial feel of volatile, low viscosity silicones to formulations while at the same time provide high viscosity and a smooth silky feel on dry-down, see for example, U.S. Pat. Nos. 5,760,116, 5,493,041 and 4,987,169.
Such polymeric silicone gels have typically been made by the hydrosilylation reaction, which requires the use of both SiH functional groups and terminal olefinic groups to form crosslinked siloxane polymers. Thus only siloxane structures that can incorporate silylhydride groups and optionally, vinyl functional siloxane groups, can be utilized in making these materials. Further this method of generating crosslinked siloxane polymers limits the range of desirable organofunctional groups that may be incorporated into the polymeric structure to create additional performance advantages in complex formulations. Thus attempts to include organofunctional groups into the crosslinked siloxane polymer include unsaturated organic groups compatible with the hydrosilylaton reaction.
SUMMARY OF THE INVENTION
The present invention provides for a method of making a cosmetic composition comprising the reaction products of
M
a
M
H
b
M
E
c
D
d
D
H
e
D
E
f
T
g
T
H
h
T
E
i
Q
j
where
M=R
1
R
2
R
3
SiO
1/2
;
M
H
=R
4
R
5
HSiO
1/2
;
M
E
=R
6
R
7
R
E
SiO
1/2
;
D=R
8
R
9
SiO
2/2
;
D
H
=R
10
HSiO
2/2
;
D
E
=R
11
R
E
SiO
2/2
;
T=R
12
SiO
3/2
;
T
H
=HSiO
3/2
;
T
E
=R
E
SiO
3/2
; and
Q=SiO
4/2
;
where R
1
, R
2
, R
3
, R
8
, R
9
and R
12
are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms; R
4
, R
5
and R
10
are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or hydrogen; R
6
, R
7
, R
11
are independently monovalent hydrocarbon radicals having from one to sixty carbon atoms or R
E
; each R
E
is independently a monovalent hydrocarbon radical containing one or more oxirane moieties having from one to sixty carbon atoms; the stoichiometric subscripts a, b, c, d, e, f, g, h, i, and j are either zero or positive subject to the following limitations: a+b+c>1; b+e+h>1; c+f+i>1; b+e+h>c+f+i; and when d+e+f+g+h+i+j=0, a+b+c=2. In a preferred embodiment the reaction product of the present invention is a polyether siloxane copolymer network. In another preferred embodiment the reaction product of the present invention is a polyether siloxane copolymer network swollen with a volatile low molecular weight silicon containing compound. These compositions are useful for a variety of personal care compositions.


REFERENCES:
patent: 3159601 (1964-12-01), Ashby
patent: 3159662 (1964-12-01), Ashby
patent: 3220972 (1965-11-01), Lamoreaux
patent: 3715334 (1973-02-01), Karstedt
patent: 3775452 (1973-11-01), Karstedt
patent: 3814730 (1974-06-01), Karstedt
patent: 4279717 (1981-07-01), Eckberg et al.
patent: 4742142 (1988-05-01), Shimizu et al.
patent: 4970252 (1990-11-01), Sakuta et al.
patent: 4980167 (1990-12-01), Harashima et al.
patent: 4987169 (1991-01-01), Kuwata et al.
patent: 5128431 (1992-07-01), Riding et al.
patent: 5138009 (1992-08-01), Inoue
patent: 5236986 (1993-08-01), Sakuta
patent: 5266321 (1993-11-01), Shukuzaki et al.
patent: 5310843 (1994-05-01), Morita
patent: 5354796 (1994-10-01), Creecy et al.
patent: 5403580 (1995-04-01), Bujanowski et al.
patent: 5412004 (1995-05-01), Tachibana et al.
patent: 5493041 (1996-02-01), Biggs et al.
patent: 5571853 (1996-11-01), Ikeno et al.
patent: 5599533 (1997-02-01), Stepniewski et al.
patent: 5599894 (1997-02-01), Ikeno
patent: 5654362 (1997-08-01), Schulz, Jr. et al.
patent: 5663752 (1997-09-01), Imamura et al.
patent: 5665804 (1997-09-01), Hill et al.
patent: 5703041 (1997-12-01), Afriat et al.
patent: 5760116 (1998-06-01), Kilgour et al.
patent: 5811487 (1998-09-01), Schulz, Jr. et al.
patent: 5833973 (1998-11-01), Dobkowski et al.
patent: 5849314 (1998-12-01), Dobkowski et al.
patent: 5854336 (1998-12-01), Divone, Sr. et al.
patent: 5859069 (1999-01-01), Yanagida
patent: 5866261 (1999-02-01), Kerr et al.
patent: 5871720 (1999-02-01), Gutierrez et al.
patent: 5880210 (1999-03-01), Schulz, Jr. et al.
patent: 5889108 (1999-03-01), Zhang
patent: 5919437 (1999-07-01), Lee et al.
patent: 5922308 (1999-07-01), Brewster et al.
patent: 5922309 (1999-07-01), Brewster
patent: 5928660 (1999-07-01), Kobayashi et al.
patent: 5929164 (1999-07-01), Zhang
patent: 5961961 (1999-10-01), Dobkowski et al.
patent: 5977280 (1999-11-01), Kadlec et al.
patent: 6024944 (2000-02-01), Hansenne
patent: 6027738 (2000-02-01), Stepniewski et al.
patent: 6039935 (2000-03-01), Mohammadi
patent: 6042815 (2000-03-01), Kellner et al.
patent: 6046156 (2000-04-01), Perry
patent: 6054547 (2000-04-01), Perry et al.
patent: 6060546 (2000-05-01), Powell et al.
patent: 6074672 (2000-06-01), Dobkowski et al.
patent: 6075111 (2000-06-01), Perry et al.
patent: 6077923 (2000-06-01), Perry et al.
patent: 6083901 (2000-07-01), Perry et al.
patent: 6153578 (2000-11-01), Perry
patent: 6365696 (2002-04-01), Westmeyer et al.
patent: 6479686 (2002-11-01), Nakanishi et al.
patent: 545 002 (1993-06-01), None
patent: 0 790 055 (1997-08-01), None
patent: 2 129 820 (1984-05-01), None
patent: 06256660 (1994-09-01), None
patent: WO 97/44010 (1997-11-01), None
patent: WO 98/00097 (1998-01-01), None
patent: WO 98/00098 (1998-01-01), None
patent: WO 98/00102 (1998-01-01), None
patent: WO 98/00103 (1998-01-01), None
patent: WO 98/00104 (1998-01-01), None
patent: WO 98/00105 (1998-01-01), None
patent: WO 98/04236 (1998-02-01), None
patent: WO 98/18438 (1998-05-01), None
patent: WO 00/08087 (2000-02-01), None
J.V. Crivello and M. Fan, J. Polymer Sci., Part A:Polymer Chemistry,pp. 1853-1863 (1997).
Advances in Organometallic Chemistry,vol. 17, pates 407 through 447, F.G.A. Stone and Robert West editors, published by the Academic Press (New York, 1979).

Affiliated with

Also associated with

Rating

Process for making cosmetic compositions using polyether... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for making cosmetic compositions using polyether..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for making cosmetic compositions using polyether... will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-3228762