Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – Liquid composition
Reexamination Certificate
2001-09-24
2004-07-27
Mruk, Brian P. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
Liquid composition
C510S221000, C510S223000, C510S224000, C510S227000, C510S230000, C510S235000, C510S418000, C510S434000, C510S441000, C510S442000, C510S443000, C510S452000, C510S471000, C134S025200, C134S025300, C134S042000
Reexamination Certificate
active
06767880
ABSTRACT:
TECHNICAL FIELD
The present invention relates to liquid dishwashing detergent compositions. More particularly, the invention relates to a process for improving the aesthetics of a liquid manual dishwashing detergent product, and a liquid automatic dishwashing detergent composition having solid particles disposed therein, the particles preferably being colored or whitened for improving aesthetics.
BACKGROUND OF THE INVENTION
The incorporation of detersive enzymes into dishwashing detergents is well known in the arena of both automatic dishwashing (ADW) formulas and liquid hand dishwashing formulas (LDLs). A recognized need in ADWs compositions is to have present one or more ingredients which improve the removal of tough foods and stains (e.g., tea, coffee, cocoa, etc.) from consumer articles. Strong alkalis like sodium hydroxide, bleaches such as hypochlorite, builders such as phosphates and the like can help in varying degrees. Moreover, improved ADWs make use of a source of hydrogen peroxide, optionally with a bleach activator such as TAED, as noted. In addition, enzymes such as commercial proteolytic and amylolytic enzymes can be used. The alpha-amylase component provides at least some benefit with respect to the starchy soil removal properties of the ADW. ADWs containing amylases typically can also deliver a somewhat more moderate wash pH in use, and can remove starchy soils while avoiding delivering large weight equivalents of sodium hydroxide on a per-gram-of-product basis.
Typically, the enzyme component of a liquid ADW composition is added to the ADW composition in liquid form. While this allows the liquid ADW composition to have the benefits of enzyme content discussed above, there are also disadvantages, most notably that the liquid ADW composition must be formulated at pH levels that are lower than those conventionally used because enzymes are rendered ineffectual after being exposed to high pH environments. Because formulating at lower pH levels can harm cleaning performance (high pH enhances cleaning by aiding the rates of hydration and hydrolysis), a need exists for an enzyme material that is stable in a high pH environment.
One approach to improving enzyme stability in a high pH (greater than 9) ADW detergent composition is to add the enzyme as a solid particle. This “enzyme particle” consists of a solid core enzyme material coated with a barrier layer material. For example, a solid enzyme material can be coated with a thick wax layer material to form an enzyme particle and then this enzyme particle may be added to the ADW composition.
But the use of these wax coatings have several disadvantages. Most notably, when the waxes melt and are released into the wash solution due to the high temperature encountered during the automatic dishwashing process, they tend to cause undesirable filming on glass, stainless steel and plastic surfaces. This filming is a particular problem with ADW formulas, which often contain no significant surfactants in the composition. Additionally, thick wax coatings can also reduce the rate of dissolution of the enzyme-containing particle, which may reduce the cleaning contribution of the enzyme, by reducing the time it is resident in the wash solution.
Given the foregoing there is a continuing need to develop new compositions for the enzyme particles that will protect the enzyme core material when the particle is added to a high pH liquid ADW composition and yet at the same time not produce the undesirable filming associated with wax coatings, nor inhibit the rapid dissolution of the enzyme-containing particles.
Accordingly, it is a benefit of the present invention that producing an enzyme particle with a two-layer coating effectively protects the core enzyme material from high pH liquid compositions, without the deleterious effects of the thick wax layer coating noted above. This two-layer consists of an interior chemical barrier, preferably an acidic barrier, which is itself coated with an exterior physical barrier. The physical barrier prevents the chemical barrier from reacting directly with the alkaline liquid product (particularly important when the chemical barrier is an acidic barrier), while the chemical barrier effectively neutralizes any stray hydroxyl groups of the alkaline product that permeate past the physical barrier coating. The chemical and physical barrier thus work together and provide complementary functions. Preferred physical barriers include polymeric coatings that are insoluble in the liquid automatic dishwashing detergent composition but soluble, meltable or dispersable under the pH, temperature and agitation conditions of an ADW device.
In addition to their use in ADW compositions, these improved enzyme particles may be incorporated into light-duty liquid (LDL) detergent compositions useful for manual dishwashing as well. Enzymes, typically commercial proteolytic and amylolytic enzymes, provide LDL compositions with a variety of benefits, including improved cleaning performance as well as preferred skin mildness and “skin feel” aesthetics (i.e. the product does not feel slimy or slippery in the hands of a consumer). By adding enzymes to a LDL composition in the form of an enzyme particle, stability of enzymes in a LDL composition, as in an ADW composition, can be enhanced. Release of the enzymes is accomplished easily as a result of the agitation and increased temperature during manual dishwashing by the consumer.
BACKGROUND ART
U.S. Pat. No. 5,164,106 discloses a non-aqueous liquid automatic dishwasher detergent composition containing a dual bleach system.
U.S. Pat. No. 5,108,641 discloses an aqueous liquid automatic dishwasher detergent composition containing a dual bleach system.
SUMMARY OF THE INVENTION
The invention meets the needs above by providing a process of improving aesthetics of a liquid dishwashing detergent product and a liquid dishwashing detergent product having enhanced aesthetics.
In one aspect of the present invention, the process of improving aesthetics of a liquid dishwashing detergent product includes the steps of providing a liquid dishwashing detergent composition and adding solid particles to the liquid dishwashing detergent composition. The particles are coated with a polymeric coating. The coating is prepared from materials which are insoluble in the liquid detergent composition but soluble in dishwashing wash solution.
In another aspect of the present invention, the liquid dishwashing detergent product having enhanced aesthetics includes a liquid dishwashing composition and solid particles. The particles are coated with a polymeric coating. The coating is prepared from materials selected from the group consisting of alkyl cellulose ethers, polyvinyl alcohol and alginate. The particles remain undissolved in said liquid dishwashing detergent composition until the composition is used either in an automatic dishwasher, or as a hand dishwashing product. The liquid dishwashing detergent product does not cause a significant increase in filming of glassware or dishware as compared to a liquid dishwashing detergent product not having the above particles, and furthermore, the liquid automatic dishwashing detergent product does not cause a significant increase in filming of glassware or dishware even in liquid compositions that do not contain any surfactants. Furthermore, the product does not leave significantly increased amounts of residue derived from the solid particles.
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Foley Peter Robert
Leyendecker Mary Ruth
Painter Jeffrey Donald
Sadlowski Eugene Steven
Song Brian Xiaoqing
Mruk Brian P.
The Procter & Gamble & Company
Waugh Kevin L.
LandOfFree
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