Process for the preparation of cyclohexane dione-(1,4)-tetrameth

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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260586R, 568648, C07C 4100

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041616146

ABSTRACT:
Cyclohexanedione-(1,4)-tetramethyl diketal of the formula ##STR1## is obtained by catalytic hydrogenation of p-benzoquinone tetramethyl diketal in a basic medium, at a temperature of from about -10.degree. to +150.degree. C. The product gives cyclohexanedione-(1,4), on acid hydrolysis, which is a valuable starting product for various syntheses, for example for tetracyanoquinodimethane, a desired compound in the field of semiconductors.
Hydroquinone dimethyl ether, which is a valuable intermediate for the dyestuff preparation, is obtained from cyclohexanedione-(1,4)-tetramethyl diketal by catalytic dehydrogenation.

REFERENCES:
patent: 3170958 (1965-02-01), Howard
patent: 4082809 (1978-04-01), Pistorius et al.
Howard et al., Jour. of Org. Chem., vol. 26 (1961) pp. 1026-1028.

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