Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...
Reexamination Certificate
2002-01-16
2003-06-03
Jones, Deborah (Department: 1775)
Stock material or miscellaneous articles
All metal or with adjacent metals
Composite; i.e., plural, adjacent, spatially distinct metal...
C428S632000, C428S650000, C428S670000, C428S699000, C428S697000, C428S701000, C428S702000, C428S469000, C416S24100B
Reexamination Certificate
active
06572981
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to protective coating systems for components exposed to high temperatures, such as the hostile thermal environment of a gas turbine engine. More particularly, this invention is directed to a process for forming an improved aluminide bond coat of a thermal barrier coating (TBC) system, such as of the type used to protect gas turbine engine components.
BACKGROUND OF THE INVENTION
Higher operating temperatures for gas turbine engines are continuously sought in order to increase their efficiency. However, as operating temperatures increase, the high temperature durability of the components of the engine must correspondingly increase. Significant advances in high temperature capabilities have been achieved through the formulation of nickel and cobalt-base superalloys. Nonetheless, when used to form components of the turbine, combustor and augmentor sections of a gas turbine engine, such alloys alone are often susceptible to damage by oxidation and hot corrosion attack and may not retain adequate mechanical properties. For this reason, these components are often protected by an environmental and/or thermal-insulating coating, the latter of which is termed a thermal barrier coating (TBC) system. Ceramic materials and particularly yttria-stabilized zirconia (YSZ) are widely used as a thermal barrier coating (TBC), or topcoat, of TBC systems used on gas turbine engine components. TBC employed in the highest temperature regions of gas turbine engines is typically deposited by electron beam physical vapor deposition (EBPVD) techniques which yield a columnar grain structure that is able to expand and contract without causing damaging stresses that lead to spallation.
To be effective, TBC systems must have low thermal conductivity, strongly adhere to the article, and remain adherent throughout many heating and cooling cycles. The latter requirement is particularly demanding due to the different coefficients of thermal expansion between ceramic topcoat materials and the superalloy substrates they protect. To promote adhesion and extend the service life of a TBC system, an oxidation-resistant bond coat is often employed. Bond coats are typically in the form of overlay coatings such as MCrAlX (where M is iron, cobalt and/or nickel, and X is yttrium or another rare earth element), or diffusion aluminide coatings. A notable example of a diffusion aluminide bond coat contains platinum aluminide (Ni(Pt)Al) intermetallic. When a bond coat is applied, a zone of chemical interaction occurs within the surface of the superalloy substrate beneath the coating. This zone is typically referred to as a diffusion zone (DZ), and results from the interdiffusion between the coating and substrate. The diffusion zone beneath an overlay bond coat is typically much thinner than the diffusion zone beneath a diffusion bond coat.
During the deposition of the ceramic TBC and subsequent exposures to high temperatures, such as during engine operation, bond coats of the type described above form a tightly adherent alumina (Al
2
O
3
) layer or scale that adheres the TBC to the bond coat. The service life of a TBC system is typically limited by a spallation event brought on by thermal fatigue. Spallation of TBC deposited on MCrAlX bond coats generally occurs within the TBC near the TBC-to-alumina interface, while TBC deposited on diffusion aluminide bond coats typically spall at the alumina-to-bond coat interface or within the alumina layer itself. As a result, the alumina-to-bond coat interface is particularly critical for TBC systems that employ diffusion aluminide bond coats because spallation events often initiate at this interface.
In view of the above, it can be appreciated that bond coats have a considerable effect on the spallation resistance of the TBC, and therefore TBC system life. Consequently, improvements in TBC life have been continuously sought, often through modifications to the chemistries of the bond coat. The effect of the surface finish of MCrAlY bond coats has also been investigated, as evidenced by U.S. Pat. No. 4,414,249 to Ulion et al. The results of this investigation showed that the service life of a columnar TBC can be improved by polishing an MCrAlY bond coat before depositing the TBC. The benefit of improving the surface finish of an MCrAlY bond coat is believed to be that a smoother alumina layer grows, which in turn provides a more uniform surface upon which the columnar TBC is deposited. The initial portion of a columnar TBC consists of many small grains that appear to grow in a competitive fashion, by which more favorably oriented grains eventually dominate less favorably oriented grains. By polishing an MCrAlY bond coat, it is believed that Ulion et al. reduced the number of nucleated grains, thereby reducing growth competition and improving the quality of the TBC adjacent the alumina scale, i.e., in the very region that TBC spallation tends to occur on an MCrAlY bond coat. According to Ulion et al., an optional additional treatment is to dry glass bead peen an MCrAlY bond coat to densify any voids and improve the coating structure.
As noted above, TBC spallation initiates by a different mechanism on diffusion aluminide bond coats, and primarily along the alumina-bond coat interface. Accordingly, the toughness of the alumina and the alumina-bond coat interface are most important to TBC deposited on a diffusion aluminide bond coat. From this perspective, improving the surface finish of a diffusion aluminide bond coat by light peening or polishing would be expected to reduce TBC life, since sufficient surface roughness of the bond coat is desired to promote adhesion of the alumina to the bond coat, and to provide a tortuous path that inhibits crack propagation through the alumina and alumina-bond coat interface. As a result, conventional practice has been to grit blast the surface of diffusion aluminide bond coats to increase their roughness to about 50 microinches (about 1.25 micrometers) Ra or more before depositing the TBC.
BRIEF SUMMARY OF THE INVENTION
The present invention generally provides a method for improving the thermal fatigue life of a thermal barrier coating (TBC) deposited on a diffusion aluminide bond coat through a process by which the surface morphology of the aluminide bond coat is modified to eliminate or at least reduce oxidation and oxidation-induced convolutions at the alumina-bond coat interface, as explained more fully below. The bond coat can be a single-phase [(Ni,Pt)Al] or two-phase [PtAl
2
+(Ni,Pt)Al] diffusion aluminide, though it is believed that overlay aluminide bond coats can also benefit from the teachings of this invention. The invention is particularly directed to aluminide bond coats deposited by methods that produce a generally columnar grain structure, in which grains extend through the additive layer of the bond coat, i.e., from the diffusion zone beneath the additive layer to the bond coat surface, such that grain boundaries are exposed at the bond coat surface. Two widely-used methods that produce bond coats of this character are vapor phase aluminizing (VPA) and chemical vapor deposition (CVD). The surface of a bond coat having columnar grains is characterized by surface irregularities, termed grain boundary ridges, that correspond to locations where grain boundaries meet the bond coat surface.
In the present invention, an aluminide bond coat having generally columnar grains and grain boundary ridges at its surface is peened at an intensity sufficient to flatten at least some of the grain boundary ridges, but insufficient to cause recrystallization of the bond coat when later heated, such as during deposition of the thermal barrier coating. In so doing, the original surface texture of the bond coat is altered to be smoother where the grain boundaries meet the bond coat surface, thereby yielding a smoother bond coat surface where the critical alumina-bond coat interface will exist following oxidation of the bond coat, such as during TBC deposition. Thereafter, the thermal barr
General Electric Company
Hartman Domenica N. S.
Hartman Gary M.
Jones Deborah
McNeil Jennifer
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