Radiant energy – Ionic separation or analysis – Methods
Reexamination Certificate
1999-09-01
2003-09-02
Anderson, Bruce (Department: 2881)
Radiant energy
Ionic separation or analysis
Methods
C250S281000, C204S157220
Reexamination Certificate
active
06614018
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention generally relates to fields of study in three broad categories: ion separation; plasma physics; and microgravity processing. Within the category of ion separation, relevant sub-fields include: mass spectroscopy, ion implantation, and isotope separation. Within the category of plasma physics are relevant sub-fields of: thermal spray and magnetohydrodynamics. Under the category of microgravity processing lie the sub-fields of: heating systems and element separation techniques. Also pertinent to this invention, but well known to those skilled in the art, are the sciences of: optics, solar power generation, material crushing or grinding, chemistry, magnetics, electrostatics, radio-frequency electromagnetics, radiative cooling, and static and dynamical mechanics. The present invention involves each of these fields, and more particularly relates to a process employing these technologies to separate isotopes in microgravity using solar power as the energy source.
2. Description of the Prior Art
In the field of mass spectroscopy, a sample is ionized and sputtered from the matrix being studied, through bombardment by another ion such as oxygen or argon. A sample analyzer segregates isotopes through the application of a magnetic field. As ions of charge q, with a velocity v and mass m pass through a magnetic field of strength B, they experience a force perpendicular to the field direction according to the Lorentz force, F=qvxB (italicized quantities are physics variables, and bolded quantities are vectors; F is force, a is acceleration, m is mass, q is electron charge, v is velocity, B is magnetic field strength, E is electric field strength, and x is the cross product operator). This force causes an acceleration in a direction normal to the original velocity according to Newton's law a=F/m. Because different ions have different masses, the acceleration they receive is different. This effect is exploited to separate out the various elements and isotopes of the matrix under study. Suitable collectors monitor the amount of charge impinging at the location associated with various isotopes, providing an indication of their presence, and an approximate indication of their relative abundance. Prior art in the field of mass spectroscopy include U.S. Pat. No. 4,066,895 to Iwanaga; U.S. Pat. No. 4,174,479 to Tuithof et al., U.S. Pat. No. 5,220,167 to Brown et al., U.S. Pat. No. 3,443,087 to Robieux et al., and U.S. Pat. No. 3,772,519 by Levy et al. This technique of magnetic separation is widely used in many fields, as will be discussed below. The current invention also uses magnetic separation as a constituent component, and as such its understanding of this field is crucial to understanding this invention. However, the means of ionization and collection are substantially different.
In the field of ion implantation, used typically for semiconductor manufacture and for impregnation of specialty materials, a gaseous molecule containing the element of interest is ionized using a radio frequency plasma. The plasma field causes dissociation of the molecule, and causes an excited state of the element to be implanted. All excited species of charge q are then accelerated using electrostatic fields of strength E according to the equation F=Eq. The accelerated ions are collimated and passed through a magnetic field to separate the various isotopes. A suitable shutter system is employed to select the ion of interest, which is then allowed to proceed toward the substrate to be implanted with this ion. However, along the beam path, between the separation magnet and the substrate, dynamic electric fields, oriented typically in two perpendicular directions to the beam axis, are employed to deflect the beam slightly. This deflection is used to cause the beam to be scanned across the substrate, typically with the desire to uniformly cover the substrate area. Once the beam arrives at the substrate, typically with a relatively high velocity and relatively low density, the ions will impinge upon the surface, and penetrate to a distance determined by the beam energy, the ion mass, the angle of incidence, and the atomic mass and crystal orientation of the substrate. Several patents in this area include U.S. Pat. No. 4,841,143 to Tamura et al., and U.S. Pat. No. 5,751,002 to Ogata et al. The present invention uses the principles of dynamically scanning a beam using electric fields, and as a preferred embodiment, will use shutters to select a specific isotope. However, the method of ionization is substantially different, and the means of collection are substantially different.
Isotope separation, as a field of study, is principally used to enrich uranium with the isotope of atomic weight 235, relative to the much more abundant U
238
. A number of patents in this field demonstrate a wide variety of techniques for achieving isotope enrichment, such as U.S. Pat. No. 3,935,451 to Janes, U.S. Pat. No. 3,940,615 to Kantrowitz, U.S. Pat. No. 4,202,860 to Miyake et al., U.S. Pat. No. 4,726,967 to Arendt et al., U.S. Pat. No. 5,024,749 to Snyder et al., U.S. Pat. No. 4,399,010 to Lyon et al., U.S. Pat. No. 5,422,481 to Louvet, U.S. Pat. No. 4,757,203 to Gil et al., U.S. Pat. No. 5,224,971 to Mukaida et al, and U.S. Pat. No. 3,953,731 to Forsen. Among the various techniques are those which use a linear direction of ion travel, and those which employ a spiral or cyclotron ion movement. In all cases, the uranium, or other element, such as zirconium, is first ionized using one of several different methods. The first broad class of ionization techniques involves first evaporating the material, and then ionizing it using radio-frequency (rf) energy or tuned laser radiation. Evaporation is accomplished with any of several techniques, such as Joule heating, laser bombardment or ion sputtering. Ionization with rf energy will typically excite all isotopes of the element of interest. However, with laser ionization, the frequency of radiation can be selected to preferentially ionize one isotope over another. This appears to be the preferred method in many patents, since it allows separation to be accomplished using electric fields, instead of magnetic fields, although both can be found in the patent records. Once the moving (linear or cyclotron) isotopes are ionized and separated by either electric or magnetic fields, they are collected at surfaces that are temperature controlled to allow condensation. This invention uses the techniques of collection of the separated ions on suitable surfaces. However, the heating method is substantially different, and there is substantially greater flexibility envisioned for the collection techniques, as will be described in the detailed description below.
The application of very rugged coatings of metal or ceramic is the goal of thermal spray. In each form, the material to be deposited is supplied in a powdered form carried in a stream of gas, such as nitrogen. The small particles of material are plasticized, melted, or ionized, depending on the energy supplied. This energy may be from the combustion of a reactive fuel with oxygen or from an electric arc. The heated particles of metal or ceramic are then carried to the substrate to be coated by the carrier gas, or by the velocity of the exit gasses from combustion. These particles then coat the surface of the substrate, preferably with very little surface reaction, and typically produce a very dense coating. Representative patents in the field of thermal spray include U.S. Pat. No. 3,892,882 to Guest et al., and U.S. Pat. No. 5,716,422 to Muffoletto et al. The current invention does not use a carrier gas, use combustion, or electric arcs, but it is a preferred embodiment of this invention that the material collected not interact with the substrate; thereby relating to this invention. Also, thermal spray is typically done in atmospheric environments, whereas the current invention is processed in the relative vacuum of space.
The principles of magnetohy
Anderson Bruce
Hartman Domenica N. S.
Hartman Gary M.
Hartman & Hartman
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