Hair dye composition

Details Hair dye composition Hair dye composition

2001-03-16

2003-07-15

Einsmann, Margaret (Department: 1751)

Bleaching and dyeing; fluid treatment and chemical modification

Dyeing involving animal-derived natural fiber material ,...

Hair dyeing

C008S406000, C008S407000, C008S409000, C008S426000, C008S437000, C008S454000

Reexamination Certificate

active

06592630

ABSTRACT:

TECHNICAL FIELD
The present invention relates to a hair dye composition which has markedly high hair dyeing power, can impart the hair with a vivid and deep color shade ranging from greenish yellow to reddish yellow, has less color fade over time and undergoes a smaller change in the color tone of the dye even after storage.
BACKGROUND ART
Hair dyes can be classified by the dye to be used therefor, or whether they have bleaching action of melanin or not. Typical examples include a two-part permanent hair dye composed of a first part containing an alkali agent, an oxidation dye and a direct dye such as nitro dye and a second part containing an oxidizing agent; and one-part semi-permanent hair dye containing an organic acid or an alkali agent, and a direct dye such as acid dye, basic dye or nitro dye.
The above-described permanent hair dye is however accompanied with the drawbacks that color tone imparted by an oxidation dye is not so vivid and the color of the hair dyed with a vivid-color producing nitro dye ordinarily employed as a direct dye markedly fades over time and becomes dull soon even if the color tone rightly after dyeing is very vivid (Japanese Patent Application Laid-Open (Kokai) No. Hei 6-271435).
Recently, hair dyes containing as a direct dye a so-called cationic dye having a cation group contained in their conjugate system have been reported (Japanese Language Laid-Open Publication (PCT) No. Hei 8-507545, 8-501322 or 10-502946, or Japanese Patent Application Laid-Open (Kokai) No. Hei 10-194942). They have been found to involve drawbacks that intended dyeing effects are not available owing to decomposition of them caused by mixing, upon hair dyeing, with hydrogen peroxide ordinarily employed as an oxidizing agent; and that when the cation group is incorporated in an azo(—N═N)-based conjugated system, they are unstable to an alkali agent or a reducing agent essentially contained in a permanent hair dye.
DISCLOSURE OF THE INVENTION
An object of the present invention is to provide a hair dye composition which features high hair dyeing power, less color fade over time and excellent storage stability permitting only a smaller color tone change of the dye after storage.
The present inventors have found that when the below-described compound which is known (in Japanese Patent Application Laid-Open (Kokai) No. Sho 53-8619) as a disperse dye for dry transfer printing of acidic modified synthetic fibers or as C.I. Basic Yellow 2 is used as a hair dye, the resulting dye composition can impart the hair with a vivid and deep color shade ranging from greenish yellow to reddish yellow without decomposing the dye upon hair dyeing, exhibits excellent light resistance, washing resistance, perspiration resistance, friction resistance and weather resistance, and undergoes a smaller change in the color tone of the dye after storage as compared with that rightly after preparation, because it exists stably in the composition.
In one aspect of the present invention, there is thus provided a hair dye composition comprising, as a direct dye, an azamethine compound represented by the following formula (1):
[wherein, R
1
, R
2
and R
3
are the same or different and each independently represents a C
1-3
alkyl group and benzene ring A or B may contain a nondissociative substituent; or the following formula (2):
In another aspect of the present invention, there is also provided a method for dyeing the hair with the above-described hair dye composition.
BEST MODE FOR CARRYING OUT THE INVENTION
Compound (1) is known in Japanese Patent Application Laid-Open (Kokai) No. Sho 53-8619 as a diperse dye for dry transfer printing of acidic modified fibers, while Compound (2) is known as C.I. Basic Yellow 2. By the use of this Compound (1) or (2) as a direct dye for a hair dye composition, the hair can be imparted with a vivid and deep color shade ranging from greenish yellow to reddish yellow.
In the formula (1), examples of the C
1-3
alkyl group represented by R
1
, R
2
or R
3
include methyl, ethyl and propyl groups.
In the formula (1), examples of the nondissociative substituent which may be possessed by benzene ring A or B include methyl group, ethyl group, propyl group, methoxy group, ethoxy group, chlorine atom and nitro group.
Specific examples of the direct dye (1) to be used in the present invention include the following compounds:
As the direct dye (1) or (2), one or more of them may be used. Alternatively, another direct dye can be used in combination. In particular, combination with a red or blue dye makes it possible to dye the hair with a deep and highly lustrous dark brown or black color.
Examples of the direct dye other than the direct dyes (1) and (2) include Basic Blue 7 (C.I. 42595), Basic Blue 26 (C.I. 44045), Basic Blue 99 (C.I. 56059), Basic Violet 10 (C.I. 45170), Basic Violet 14 (C.I. 42515), Basic Brown 16 (C.I. 12250), Basic Brown 17 (C.I. 12251), Basic Red 2 (C.I. 50240), Basic Red 22 (C.I. 11055), Basic Red 76 (C.I. 12245), Basic Red 118 (C.I. 12251:1) and Basic Yellow 57(C.I. 12719); and basic dyes as described in Japanese Patent Publication No. Sho 58-2204, Japanese Patent Application Laid-Open No. Hei 9-118832, Japanese Language Laid-Open Publication (PCT) No. Hei 8-501322 or Japanese Language Laid-Open Publication (PCT) No. Hei 8-507545.
The direct dye (1) or (2) is preferably added in an amount of 0.01 to 20 wt. %, more preferably 0.05 to 10 wt. %, especially 0.1 to 5 wt. % on the basis of the entirety of the composition (after mixing of all the parts when a two-part or three-part composition is employed; this will apply equally hereinafter). When another direct dye is used in combination, the content of it with the direct dye (1) or (2) preferably ranges from 0.05 to 10 wt. %, especially 0.1 to 5 wt. % based on the whole composition.
The hair dye composition of the present invention is preferably adjusted to pH 6 to 11, with pH 8 to 11 being more preferred. Examples of the alkali agent to be used for pH adjustment includes ordinarily employed ones such as ammonia, organic amines and salts thereof. The alkali agent is preferably added in an amount of 0.01 to 20 wt. %, more preferably 0.1 to 10 wt. %, especially 0.5 to 5 wt. %.
In the hair dye composition of the present invention, an oxidizing agent can be incorporated. In this case, hair dyeing and bleaching can be carried out simultaneously, which facilitates more vivid hair dyeing. Ordinarily employed oxidizing agents, for example, hydrogen peroxide, persulfates such as ammonium persulfate, potassium persulfate and sodium persulfate, perborates such as sodium perborate, percarbonates such as sodium percarbonate and bromates such as sodium bromate and potassium bromate are usable. Out of them, hydrogen peroxide is especially preferred. The oxidizing agent is added in an amount of 0.5 to 10 wt. %, especially 1 to 8 wt. %, on the basis of the entirety of the composition.
In the hair dye composition of the present invention, an oxidation dye can be incorporated further. This incorporation enables markedly vivid dyeing not attainable by the single use of an oxidation dye. As the oxidizing agent, the above-exemplified oxidizing agents can be used, with hydrogen peroxide being particularly preferred. Alternatively, an oxidizing enzyme such as laccase can be employed. For the oxidation dye, known developers and couplers ordinarily employed for an oxidation type hair dye can be used.
Examples of the developer include p-phenylenediamines having one or several groups selected from NH
2
—, NHR— and NR
2
-groups (R represents a C
1-4
alkyl or hydroxyalkyl group) such as p-phenylenediamine, p-toluylenediamine, N-methyl-p-phenylenediamine, chloro-p-phenylenediamine, 2-(2′-hydroxyethylamino)-5-aminotoluene, N,N-bis-(2-hydroxyethyl)-p-phenylenediamine, 2-hydroxyethyl-p-phenylenediamine, 2,6-dimethyl-p-phenylenediamine, methoxy-p-phenylenediamine, 2,6-dichloro-p-phenylenediamine, 2-chloro-6-methyl-p-phenylenediamine, 6-methoxy-3-methyl-p-phenylenediamine, 2,5-diaminoanisole, N-(2-hydroxypropyl)-p-phenylenediamin

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