Arthropod-controlling composition

Plant protecting and regulating compositions – Plant growth regulating compositions – Organic active compound containing

Reexamination Certificate

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C549S291000

Reexamination Certificate

active

06509298

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to an arthropod-controlling composition.
BACKGROUND OF THE INVENTION
Many arthropod-controlling compositions are on the market at present. However, the objected harmful arthropods have many kinds and the situations for controlling them are in many ways. Therefore, the arthropod-controlling composition having practically high effectiveness and safety is desired.
Though pyrethroid insecticides having rapid knock-down efficacy are excellent agents for controlling harmful arthropods, progress of pyrethroid resistance to some arthropods has been reported in various places recently. Under these circumstances, non-pyrethroid compounds having excellent knock-down efficacy are earnestly desired.
On the other hand, it is known that some &agr;-pyrone compounds are effective for controlling harmful acarina and houseflies in Japanese Unexamined Patent Publication No. sho-51-19126. However, the compounds described in the publication do not necessarily give a sufficient effect.
SUMMARY OF THE INVENTION
The present invention provides 4-hydroxy-6-methyl-3-(3-methylbutanoyl)-2-pyrone shown by the formula:
an arthropod-controlling composition comprising it as an active ingredient and a method for controlling arthropods by using it.
DETAILED DESCRIPTION OF THE INVENTION
Examples of the arthropods against which 4-hydroxy-6-methyl-3-(3-methylbutanoyl)-2-pyrone (hereinafter referred as to The Pyrone Compound) exhibits a control effect include the following Insecta, Acarina, Chilognatha, Epimorpha and Isopoda:
Hemiptera Insects:
Delphacidae (planthoppers) such as
Laodelphax striatellus
(small brown planthopper),
Nilaparvata lugens
(brown planthopper),
Sogatella furcifera
(white-backed rice planthopper) and so on; Deltocephalidae (leafhoppers) such as
Nephotettix cincticeps
(green rice leafhopper),
Recilia dorsalis
(zig-zag rice leaf hopper),
Nephotettix virescens
(green rice leafhopper) and so on; Aphididae (aphids); stink bugs; Aleyrodidae (whiteflies); scales; Tingidae (lace bugs); Psyllidae (suckers) and so on.
Lepidoptera Insects:
Pyralidae such as
Chilo suppressalis
(rice stem borer),
Cnaphalocrocis medinalis
(rice leafroller),
Plodia interpunctella
(Indian meal moth) and so on; Noctuidae such as
Spodoptera litura
(tobacco cutworm),
Pseudaletia separata
(rice armyworm),
Mamestra brassicae
(cabbage armyworm) and so on; Pieridae such as
Pieris rapae crucivora
(common cabbageworm) and so on; Tortricidae such as Adoxophyes spp. and so on; Carposinidae; Lyonetiidae; Lymantriidae; Plusiinae; Agrotis spp. such as
Agrotis segetum
(turnip cutworm),
Agrotis ipsilon
(black cutworm) and so on; Helicoverpa spp.; Heliothis spp.;
Plutella xylostella; Parnara guttata
(rice skipper);
Tinea pellionella
(casemaking clothes moth);
Tineola bisselliella
(webbing clothes moth) and so on.
Diptera Insects:
Culex spp. such as
Culex pipiens pallens
(common mosquito),
Culex tritaeniorhynchus
and so on, Aedes spp. such as
Aedes aegypti, Aedes albopictus
and so on; Anopheles spp. such as
Anopheles sinensis
and so on; Chironomidae (midges); Muscidae such as
Musca domestica
(housefly),
Muscina stabulans
(false stablefly),
Fannia canicularis
(little housefly) and so on; Calliphoridae; Sarcophagidae; Anthomyiidae such as
Delia platura
(seedcorn maggot),
Delia antiqua
(onion maggot) and so on; Tephritidae (fluit flies); Drosophilidae; Psychodidae (moth flies); Tabanidae; Simuliidae (black flies); Stomoxyidae (stable flies); Phoridae; Ceratopogonidae (biting midges) and so on.
Coleoptera Insects (Beetles)
Corn rootworms such as
Diabrotica virgifera
(western corn rootworm),
Diabrotica undecimpunctata howardi
(southern corn rootworm) and so on; Scarabaeidae (scarabs) such as
Anomala cuprea
(cupreous chafer),
Anomala rufocuprea
(soybean beetle) and so on; Curculionidae (weevils) such as
Sitophilus zeamais
(maize weevil),
Lissorhoptrus oryzophilus
(ricewater weevil), ball weevil,
Callosobruchus chinensis
(adzuki bean weevil) and so on; Dermestidae such as
Authrenus verbasci
(varied carpet beetle),
Attagenus unicolor japonicus
(black carpet beetle) and so on; Tenebrionidae (darkling beetles) such as
Tenebrio molitor
(yellow mealworm),
Tribolium castaneum
(red flour beetle) and so on; Chrysomelidae (leaf beetles) such as
Oulema oryzae
(rice leaf beetle),
Phyllotreta striolata
(striped flea beetle),
Aulacophora femoralis
(cucurbit leaf beetle) and so on; Anobiidae; Epilachna spp. such as
Epilachna vigintioctopunctata
(twenty-eight-spotted ladybird) and so on; Lyctidae (powderpost beetles), Bostrychidae (false powderpost beetles), Cerambycidae,
Paederus fuscipes
(robe beetle) and so on.
Dictyoptera Insects:
Blattella germanica
(German cockroach);
Periplaneta fuliginosa
(smokybrown cockroach);
Periplaneta americana
(American cockroach);
Periplaneta brunnea
(brown cockroach);
Blatta orientalis
(oriental cockroach) and so on.
Thysanoptera Insects (Thrips):
Thrips palmi, Flankliniella occidentalis
(western flower thrips),
Thrips hawaiiensis
(flower thrips) and so on.
Hymenoptera Insects:
Formicidae (ants); Vespidae (hornets); Polistes spp. (long-legged wasps); Bethylidae; Tenthredinidae (sawflies) such as
Athalis rosae ruficornis
(cabbage sawfly) and so on.
Orthoptera Insects:
Gryllotalpidae (mole crickets); Acrididae (grasshoppers) and so on.
Siphonaptera Insects (Fleas):
Ctenocephalides canis
(dog flea);
Ctenocephalides felis
(cat flea);
Pulex irritans
; and so on.
Anoplura Insects (Lice):
Pediculus corporis
(body louse);
Pediculus humanus
(head louse);
Pthirus pubis
(crab louse) and so on.
Isoptera Insects:
Reticulitermes speratus;
Coptotermes formosanus
(Formosan subterranean termite); and so on.
Harmful Acarina:
Ixodidae (Ticks):
Boophilus microplus; Haemaphysalis longiconis
and so on Tetranychidae (spider mites):
Tetranychus cinnabarinus
(carmine spider mite);
Tetranychus urticae
(two-spotted spider mite);
Tetranychus kanzawai
(Kanzawa spider mite);
Panonychus citri
(citrus red mite);
Panonychus ulmi
(European red mite) and so on.
House-dust Mites:
Acaridae such as Tyrophagus putrescentiae (copra mite),
Aleuroglyphus ovatus
(brown legged grain mite) and so on; Dermanyssidae such as
Dermatophagoides farinae
(American house dust mite),
Dermatophagoides pteronyssinus
and so on; Glycyphagidae such as
Glycyphagus privatus, Glycyphagus domesticus, Glycyphagus destructor
and so on; Cheyletidae such as
Chelacaropsis malaccensis, Cheyletus fortis
and so on; Tarsonemidae; Chortoglyphus spp.; Haplochthonius spp. and so on.
Chilognatha (millipedes) such as Oxydus spp.; Chilopoda (centipedes) such as red centipede; wood lice such as Porcellio spp., Porcellionides spp.; and pill bugs such as Armadillidium spp. ;and so on.
As The Pyrone Compound, which is an active ingredient of the present controlling agent, gives an efficacy by contacting the objective harmful arthropods including insects and acarina, it is usually to be formulated as described below for use.
Namely, The Pyrone Compound or its solution can be formulated to the present controlling agent such as oil solution, emulsifiable concentrate, wettable powder, flowable (aqueous suspension or aqueous emulsion), granule, dust and so on, by mixing with solid carrier, liquid carrier or liquefied gaseous carrier and optionally surfactant, the other formulation auxiliaries.
The present controlling agent described above contains usually 0.001 to 95% by weight of The Pyrone Compound as an active ingredient.
Examples of the solid carrier used in the formulation described above include fine granules or granules of inorganic carriers such as clays (e.g. kaolin clay, diatomaceous earth, synthetic hydrated silicon oxide, bentonite, Fubasami clay, acid clay, etc.), talc, ceramics, sericite, quartz, calcium carbonate and so on; synthetic resins such as polyethylene, polypropylene and so on; and carriers originated from plants such as wood powder, activated carbon and so on. Examples of the liquid carrier include water, alcohol

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