Catalytic process for the manufacture of urethanes

Details Catalytic process for the manufacture of urethanes Catalytic process for the manufacture of urethanes

1979-05-25

1981-05-05

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

260464, 260465D, 2604654, 560 9, 560 25, 560 26, 560 27, 560 29, 560 30, 560 31, 560 32, 560 33, 560115, 560132, 560133, 560135, 560136, 560137, 560148, 560157, 560158, 560159, 560160, 560161, 560162, 560163, 560164, 560165, 252438, 525439, 252440, 252441, 252472, C07C125063, C07C12507

Patent

active

042660700

ABSTRACT:
A process for the production of urethanes is provided in which an organic primary or secondary amine is contacted, in the substantial absence of reactive oxygen, with a source of carbon monoxide and an organic compound containing at least one hydroxyl group in the presence of a catalyst comprising a member selected from the group consisting of carbonyls of Co, Mo, Ti, Rh, Fe, Ni and mixtures thereof. Urethane yields and selectivities are further improved by conducting the reaction in the additional presence of an organic compound containing at least one C.dbd.N or C.dbd.C group. When such unsaturated organic compounds are employed, the catalyst can additionally comprise iridium carbonyl.

REFERENCES:
patent: 3099689 (1963-07-01), Cragg
patent: 3338956 (1967-08-01), Morentfield
patent: 3384655 (1968-05-01), Anderson et al.
patent: 3448140 (1969-06-01), Gamlen et al.
patent: 3454620 (1969-07-01), Gamlen et al.
patent: 3467694 (1969-09-01), Hardy et al.
patent: 3531512 (1970-09-01), Hardy et al.
patent: 3629311 (1971-12-01), Anderson et al.
patent: 3895054 (1975-07-01), Zajacek et al.
patent: 3956360 (1976-05-01), Zajacek et al.
patent: 3993685 (1976-11-01), Zajacek et al.
patent: 3993685 (1976-11-01), Zajacek et al.
patent: 4052437 (1977-10-01), Licke
patent: 4080365 (1978-03-01), Hirai et al.
patent: 4100351 (1978-07-01), Romono et al.
patent: 4134880 (1969-01-01), Miyata et al.
patent: 4170708 (1979-10-01), Hirai et al.
patent: 4178455 (1979-12-01), Hirai et al.
patent: 4186269 (1980-01-01), Hirai et al.
Balling, et al., "Chem. Absts." 73, 66302 (p) 1970.
Franz et al., J. Org. Chem., 26, 3309 (1961).
Baiocchi, et al., J. Org. Chem., 21, 1546, 1956.

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