Difluoroketones from difluoroacylsilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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549214, C07F 718

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active

049963457

ABSTRACT:
A process for the synthesis of alpha,alpha-difluoroketones from alpha,alpha-difluoroacylsilanes and intermediates therefor.

REFERENCES:
patent: 2892859 (1959-06-01), McBee et al.
patent: 4692537 (1987-09-01), McAlister
patent: 4933510 (1990-06-01), Magnusson et al.
Metcalf et al., Tet. Letters 26, 2861-2864, (1985).
Yuan et al., J. Am. Chem. Soc. 109, 8071-8081, (1987).
Gelb, M. H., J. Am. Chem. Soc. 108, 3146-3147, (1986).

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