Intramolecular migration reactions

Details Intramolecular migration reactions Intramolecular migration reactions

1989-11-08

1991-02-26

Prescott, Arthur C.

Organic compounds -- part of the class 532-570 series

Organic compounds

Aluminum containing

556170, 556183, 556187, 585601, C07F 506, C07C 276

Patent

active

049963406

ABSTRACT:
A novel migratory insertion reaction is disclosed utilizing organoaluminum compounds. An intramolecular transfer of a carbon group from the aluminum complex E-1-halo-1-alkenyl)trialkylalanate occurs to produce an E-alkenyl(alkoxy)dialkylalanate or an E-dialkylalkenylalane or an (E,E)-3-alkyl-2-dialkylalumino-1,3-diene depending on process conditions. Novel organic aluminates are also disclosed.

REFERENCES:
patent: 3686250 (1972-08-01), Lanier
patent: 3829520 (1974-08-01), Ferrell
patent: 4133815 (1979-01-01), Watson et al.
patent: 4251453 (1981-02-01), Garrison

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