Prototyping of patterned functional nanostructures

Details Prototyping of patterned functional nanostructures Prototyping of patterned functional nanostructures

2001-04-20

2002-10-29

Brunsman, David (Department: 1755)

Compositions: coating or plastic

Coating or plastic compositions

Silicon containing other than solely as silicon dioxide or...

C106S287110, C106S287130, C106S287140, C427S256000, C427S387000, C101S450100, C347S096000

Reexamination Certificate

active

06471761

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to patterned nanostructures, and more particularly to patterned functional nanostructures.
2. Description of the Prior Art
Marine organisms like diatoms and radiolaria provide many examples of intricately organized architectures preserved in silica or calcium carbonate. Such natural microsturctures are formed by biomineralization, a templated self-assembly process in which preorganized organic surfaces regulate the nucleation, growth, morphology and orientation of inorganic crystals. To date, a variety of synthetic pathways that mimic aspects of biomineralization have been explored to prepare patterned ceramic materials.
Hierarchical materials assembly strategies have been developed which allowed growing surfactant-templated mesoporous silica in solution route on hydrophobic patterns prepared by micro-contact printing (&mgr;CP). The films formed by this technique are usually noncontinuous and have globular morphologies. In addition it takes days to form nanostructures using &mgr;CP. Oriented mesoporous silica patterns, using a micro-molding in capillary (MIMIC) technique can be made. However, it requires hours to form such ordered structures under electric field.
Although progress has been made in the preparation of a wide variety of patterned ceramic materials, current synthetic methods have several inherent drawbacks from the standpoint of nanotechnology: First, most templating procedures are conducted in time-consuming batch operations often employing hydrothermal processing conditions. Second, the resultant products are typically ill-defined powders, precluding their general use in thin film technologies. Third, procedures developed to date are often limited to forming patterns of pores.
For many envisioned nanotechnologies, it would be desirable to create patterned nanocomposites consisting of periodic arrangements of two or more dissimilar materials. None of the existing technologies provide a means to fulfill the above need.
Soft lithography approaches have been combined with surfactant and particulate templating procedures to create oxides with multiple levels of structural order. However, materials thus formed have been limited primarily to oxides with no specific functionality, whereas for many of the envisioned applications of hierarchical materials, it is necessary to define both form and function on several length scales. In addition the patterning strategies employed thus far require hours or even days for completion.
Such a long processing time is not very useful in further developing nanotechnologies because slow processes are inherently difficult to implement in commercial environments. Hence a rapid method that enables one to form hierarchically organized structures on substrates in a matter of seconds is highly desirable.
SUMMARY OF THE INVENTION
It is therefore an object of the present invention to form hierarchically organized structures on substrates in a matter of seconds.
It is a further object of the present invention to form patterned nanocomposites that will provide materials suitable for use in nanotechnologies.
It is a further object of the present invention to form nanocomposite materials exhibiting multiple levels of structural order and function on multiple length scales.
It is yet another object of the present invention to form homogeneous mesoporous thin-films.
It is yet another object of the present invention to provide a means to form highly oriented particulate mesophases on a substrate.
It is yet another object of the invention to provide approaches to tailor materials structure and function on multiple length scales i.e., micro-, meso-, and macro-scopic scales and at multiple locations for device fabrications.
According to a first broad aspect, the present invention provides a coating composition comprising: TEOS; a surfactant; at least one organosilane; HCl; water; and ethanol.
According to a second aspect of the present invention, there is provided a method for forming a film comprising: providing at least one coating composition comprising: TEOS; a surfactant; at least one organosilane; HCl; water; and ethanol; applying the coating composition on a substrate to form a coating on the substrate; and drying the coating to form a patterned silsequioxane film.
Other objects and features of the present invention will be apparent from the following detailed description of the preferred embodiment.


REFERENCES:
McDonald, Functioning Nanostructures Self-Assemble Out of Ink, Posted May 8, 2000, http://www.amtexpo.com
ano/messages/255.html.*
Brinker et al., “Evaporation-Induced Self-Assembly: Nanostructures Made Easy,”Advanced Materials,(1999,) No month provided, 11, No. 7.
Lu et al., “Evaporation-Induced Self-Assembly of Hybrid Bridged Silsesquioxane Film and Particulat Mesophases with Integral Organic Functionality,”J. Am. Chemn. Soc.(2000), No date provided, 122, 5258-5261. (Jun. 2000),
Lu et al, “Continuous formation of supported cubic and hexagonal mesoporous films by sol-gel dip-coating,”Nature, vol. 389, 25 (Sep., 1997).
Fan et al., “Rapid prototyping of patterned functional nanostructures,” The University of New Mexico Center for Micro-Engineered Materials and Department of Chemical and Nuclear Engineering, Albuquerque, NM 87131, Sandia National Laboratories, Albuquerque, New Mexico 87185. No date provided (May 2000).

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