Aqueous carbon black dispersions

Details Aqueous carbon black dispersions Aqueous carbon black dispersions

2000-07-21

2002-09-17

Klemanski, Helene (Department: 1755)

Compositions: coating or plastic

Coating or plastic compositions

Marking

C106S031650, C106S031750

Reexamination Certificate

active

06451100

ABSTRACT:

CROSS-REFERENCE TO RELATED APPLICATION
This application relates to German Application DE 199 34 281.4, filed Jul. 21, 1999, which disclosure is incorporated herein by reference.
FIELD OF THE INVENTION
The invention concerns aqueous, cationically stabilized carbon black dispersions, a method of their production and their use.
BACKGROUND OF THE INVENTION
Aqueous carbon black dispersions are used in formulations for printing inks and also directly as inks, for example, in inkjet printers.
The inkjet printing method is a known reproducing technology in which the printing ink is transferred without pressure, that is, without contact of the print head with the print medium. Droplets of ink are sprayed from a jet or nozzle onto a receiving material during which deflection of the droplets can be electronically controlled. This technology, also known as pressureless printing, is particularly suitable for printing products having irregular surfaces and packaging because there is a certain distance between the print head and the printed material. The printing method is very flexible and relatively economical and is therefore also used in computer printing, for example, as a workplace printer. The inkjet method is also increasingly used in the industrial field, for example, in outside advertising. In outside advertising, the ink must meet special requirements of light-fastness and water resistance. In addition, the coloring components must be very finely divided in order to prevent the printing jets from clogging. Both dyes as well as, more recently, pigments have been used as coloring substances. Pigments have advantages over dyes in that the light-fastness of pigments is very high and that pigments are water-resistant. Pigments have a disadvantage in comparison to dyes, namely that they only form stable dispersions with a long storage life when treated with surface-active substances (surfactants). Pigment particles are not present in the form of primary particles but rather in the form of aggregates. Pigment aggregates are larger than soluble dyes. If pigment aggregates are not sufficiently finely dispersed, they clog the jets of printing heads. Moreover, large aggregates alter the light absorption properties of pigment black. The result is a graying of the print and a loss of covering power.
Early patents that disclose the use of carbon blacks as pigment blacks in inkjet inks are U.S. Pat. Nos. 5,085,698 and 5,320,668. the use of water-soluble acrylates for pigment stabilization is described therein.
The production of aqueous carbon black dispersions with carbon blacks having an average primary particle size of not greater than 30 nm and a DBP No. of at least 75 ml/100 g is known (U.S. Pat. No. 5,538,548).
The production of aqueous carbon black dispersions using water-soluble organic solvents and water-soluble acrylic resins is also known (U.S. Pat. No. 5,609,671).
A disadvantage of the known aqueous carbon black dispersions is running or bleeding after the dispersions have been sprayed onto a carrier. Commercial dispersions have zeta potentials <0 mV. A purposeful flocculation of the dispersion during or after its application onto the carrier can be readily achieved by positive surface charging of the dispersed particles (zeta potentials >0 mV), which counteracts bleeding.
SUMMARY OF THE INVENTION
It is an object of the invention problem to produce carbon black dispersions that do not have the disadvantages mentioned above and that, in addition, are stable during storage.
The invention has as its subject matter aqueous carbon black dispersions containing the following components in addition to water, relative to the total dispersion:
Carbon black: 1 to 45% by weight, preferably 5 to 25% by weight; and
Cationic surfactant: 1 to 40% by weight, preferably 5 to 25% by weight,
Compounds with the following formula can be used as cationic surfactants:
R
1
—COOH: ricinoleic acid
R
2
, R
3
, R
4
: may be identical or different and may consist of C
1
to C
5
alkyl groups, or
R
5
: C
1
to C
5
alkyl groups,
n: natural number 1-5,
In one embodiment, the cationic surfactant can be a wetting agent combination or carbon blacks with an average primary particle size of 8 to 80 nm, preferably 10 to 35 nm and a DBP number of 40 to 200 ml/100 g, preferably 60 to 150 ml/100 g can be used as the pigment carbon black. Pigment carbon blacks produced by means of furnace black methods, gas black methods, channel black methods or flame black methods can be used as pigment carbon blacks. Examples thereof are color black FW 200, color black FW 2, color black FW 2 V, color black FW 1, color black FW 18, color black S 170, color black S 160, special black 6, color black 5, color black 4, color black 4A, Printex 150 T, Printex U, Printex V, Printex 140 U, Printex 140 V, Printex 95, Printex 90, Printex 85, Printex 80, Printex 75, Printex 55, Printex 45, Printex 40, Printex P, Printex 60, Printex XE 2, Printex L 6, Printex L, Printex 300, Printex 30, Printex 3, Printex 35, Printex 25, Printex 200, Printex A, Printex G, color black 550, color black 350, color black 250, color black 100, made by Degussa-Hüls AG, Germany. In a preferred embodiment of the invention gas blacks can be used.
The carbon black dispersed in the dispersion can have an average particle size of 50 to 250 nm in an embodiment of the invention.
Further subject matter of the invention comprises a method of producing an aqueous carbon black dispersion that is characterized in that carbon black is dispersed together with a wetting agent or wetting agents in water and that bead mills, ultrasonic devices or an Ultra-Turrax Mixer are used, if necessary, for dispersal. Following dispersal, the carbon black dispersion can be centrifuged or filtered.
The pH of the dispersions can be in the acidic range, preferably in the pH range of 1-4.
The dispersions in accordance with the invention have a very high flocculation stability at an acidic pH and therefore have a high stability during storage.
The carbon black dispersions in accordance with the invention have conventional optical density.
The aqueous carbon black dispersions in accordance with the invention can be used for producing inks, lacquers and printing inks, in particular inks for inkjet printers.
DETAILED DESCRIPTION OF THE INVENTION


REFERENCES:
patent: 5919294 (1999-07-01), Hirasa et al.
patent: 5993527 (1999-11-01), Tochihara et al.
patent: 6171382 (2001-01-01), Stubbe et al.

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