Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
1999-06-02
2002-05-21
Warden, Jill (Department: 1743)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S119000, C510S125000, C510S126000, C510S130000, C516S203000
Reexamination Certificate
active
06391834
ABSTRACT:
BACKGROUND OF INVENTION
1. Field of the Invention
This invention relates to foaming body-cleansing compositions in the form of a liquid surfactant composition based on a combination of high-foaming anionic surfactants and foam-boosting alkyl (poly)glycosides which contain a combination of a zwitterionic surfactant and an ampholytic surfactant for further improving the properties of the foam, more particularly its fine-bubble character and its stability (creaminess).
Liquid body-cleansing compositions which are marketed, for example, as liquid soaps, shampoos, shower bath preparations and foam bath additives are not only expected to have a good cleansing effect, they are also expected to show high skin and mucous membrane compatibility and not to overly degrease or dry the skin, even in the event of frequent use. In addition to this, however, consumers also evaluate performance properties according to the quality and quantity of the foam formed in use. In particular, consumers look for rapid initial foaming with formation of a fine-bubble and stable foam, these properties of the foam also being generally described as creaminess.
The body-cleansing formulations themselves are also expected to be distinguished by a certain viscosity so that, for example, they can be applied to the hand and do not trickle through the fingers before they can be spread over the body or the head.
There are many known surfactants which are kind to the skin and compatible with the mucous membrane. However, there are only a few surfactants which meet the additional need for a certain viscosity of the aqueous solution and for a fine-bubble character of the foam. For this reason, combinations of various surfactants have always been used hitherto in order to satisfy these various requirements. Thus, a combination of alkyl ether sulfate surfactants and alkyl (poly)glucosides has proved to be particularly high-foaming and dermatologically compatible. In addition, zwitterionic surfactants or betaine surfactants and ampholytic surfactants are known for their ability, in combination with anionic surfactants, to improve the dermatological compatibility of those surfactants and to Impart a relatively high viscosity to aqueous preparations or to improve their thickenability by electrolyte salts.
2. Discussion of Related Art
DE-A-42 34 487, for example,describes an aqueous detergent composition containing alkyl sulfate surfactants, alkyl ether sulfate surfactants, alkyl (oligo)glucosides and amphoteric or zwitterionic surfactants.
However, it has now been found that the properties of the foam, more especially its fine-bubble character and stability, can be further improved by using a combination of a zwitterionic surfactant and an ampholytic surfactant instead of a betaine surfactant or ampholytic surfactant.
DESCRIPTION OF THE INVENTION
Accordingly, the present invention relates to aqueous body-cleansing compositions containing high-foaming, dermatologically compatible anionic surfactants (A) and alkyl (oligo)glycosides (B), characterized in that they contain a combination of a zwitterionic surfactant (C) corresponding to formula I:
and an ampholytic surfactant (D) corresponding to formula II:
in which R
1
is an alkyl or alkenyl group containing 12 to 18 carbon atoms or a group R
5
—CONH—(CH
2
)
n
, where R
5
is an alkyl or alkenyl group containing 12 to 18 carbon atoms and n is a number of 2 to 4, and R
2
, R
3
and R
4
are alkyl groups containing 1 to 4 carbon atoms or hydroxyalkyl groups containing 2 or 3 carbon atoms,
in a ratio by weight of (A) to (B) to (C+D) of 10:(0.5-5):(1-5)
in order further to improve their foam properties and their viscosity.
High-foaming, dermatologically compatible anionic surfactants (A) are known to the expert in large numbers from relevant handbooks and are commercially available. More particularly, they are alkyl sulfates in the form of their ammonium or alkanolammonium salts, alkyl ether sulfates, alkyl ether carboxylates, acyl isethionates, acyl sarcosinates, acyl taurines with linear alkyl or acyl groups containing 12 to 18 carbon atoms and in the form of their alkali metal or ammonium salts. The anionic surfactants (A) may be present in the compositions according to the invention in a quantity of 3 to 30% by weight. Particularly preferred anionic surfactants are alkyl ether sulfates. Accordingly, at least one alkyl ether sulfate surfactant corresponding to the formula III:
R
6
O(C
2
H
4
O)
m
—SO
3
(−)
M
(+)
(III)
in which R
6
is an alkyl or alkenyl group containing 12 to 18 carbon atoms, m=1-4 and M
(+)
is an alkali metal, magnesium, ammonium or alkanol-ammonium ion, is preferably present as the anionic surfactant in a quantity of at least 5% by weight, based on the composition as a whole.
Alkyl (oligo)glycosides (B) are well-known surface-active substances which can be produced from sugars and aliphatic primary alcohols containing 8 to 22 carbon atoms by acetalization. Sugar components (glycoses) include—preferably—glucose and also fructose, mannose, galactose, talose, gulose, allose, idose, arabinose, xylose, lyxose, ribose and mixtures thereof. The acetalization products of glucose with fatty alcohols obtainable, for example, from natural oils and fats by known methods are preferably used by virtue of their ready accessibility and their favorable applicational properties.
So far as the glycoside unit is concerned, both monoglycosides and oligoglycosides where a sugar unit is attached to the fatty alcohol by a glycosidic bond are suitable. Mixtures of mono- and oligoglucosides are usually present in the commercially available products.
Preferred alkyl (oligo)glycosides (B) are those with the formula R
7
(G)
x
, where R
7
is a linear alkyl group containing 8 to 16 carbon atoms and (G)
x
is an (oligo)glucoside unit with an average degree of oligomerization x of 1 to 2.
Such products are commercially available, for example, under the trade mark Plantaren® or Plantacare®.
Zwitterionic surfactants (C) corresponding to formula I are also well-known and are commercially available in large numbers. The most well-known and most widely used group of these surfactants are the betaine surfactants in which R
2
and R
3
are methyl groups. Among the betaine surfactants, there are the alkyl betaines where R
1
is an alkyl or alkenyl group and the amidobetaines where R
1
is a group R
5
CONH—(CH
2
)
n
—. A cocoamidopropyl betaine of formula I, where R
1
is a group R
5
CONH—(CH
2
)
3
—, in which R
5
CO is derived from a C
12-18
cocofatty acid or palm kernel oil fatty acid, and R
2
and R
3
are methyl groups, is preferably used for the purposes of the invention. Such products are commercially available, for example, under the trade mark Dehyton®K.
Ampholytic surfactants (D) corresponding to formula II are also known and commercially available surfactants. They have the ability to react like cationic surfactants in acidic solution by protonation at the tertiary nitrogen atom and like anionic surfactants in the alkaline range by salt formation at the carboxyl group. A preferred ampholytic surfactant (D) is a cocoamphoglycinate corresponding to formula II where R
1
is a group R
5
CONH—(CH
2
)
2
—, in which R
5
CO is derived from a C
12-18
cocofatty acid or palm kernel oil fatty acid, and R
4
is a hydroxyethyl group. One such surfactant is commercially available, for example, under the trade mark Dehyton®G.
Particularly favorable foam properties, more especially fine bubbles and creaminess, are obtained when the zwitterionic surfactant (C) and the ampholytic surfactant (D) are present in a ratio by weight of (C) to (D) of 1:(0.1-0.5).
Besides the compulsory components (A), (B), (C) and (D), the foaming aqueous preparations according to the invention may also contain other surfactants and additives. In quantitative terms, these other ingredients together should not make up any more than component (A).
Suitable other additives are, for example, nonionic surfactants, water-soluble polymers, for example cationic polymeric conditioners, pearlesc
Schelges Heike
Scholz Wolfhard
Schosser Gryta
Cross LaToya
Harper Stephen D.
Henkel Kommanditgesellschaft auf Aktien
Hild Kimberly R.
Murphy Glenn E. J.
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