Radiant energy – Invisible radiant energy responsive electric signalling – Infrared responsive
Reexamination Certificate
2000-07-24
2002-08-27
Epps, Georgia (Department: 2873)
Radiant energy
Invisible radiant energy responsive electric signalling
Infrared responsive
C250S338200, C250S338300, C250S338400
Reexamination Certificate
active
06441374
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to thermal type infrared ray detector with a thermal separation structure.
2. Description of the Related Art
As an infrared ray detecting device, a detecting device of a thermal separation structure is known as “Monolithic Silicon Micro-bolometer Arrays” in “Uncooled Infrared Imaging Arrays and Systems” by R. A. Wood, (Semiconductors and Semimetals, Volume 47, volume editors P. W. Kruse and D. D. Skatrud, Academic Press, 1997, p103). 
FIGS. 1 and 2
 show such a thermal separation structure of a picture element of a bolometer type uncooled infrared sensor array. As shown in 
FIGS. 1 and 2
, a readout circuit 
102
 for bolometer is formed in a Si substrate 
101
, and a diaphragm 
105
 is supported by two beams 
104
 to form an air gap 
103
 between a semiconductor 
101
 and the diaphragm 
105
. The structure material of the beam 
104
 is a protective insulating film 
106
 of silicon nitride and the thickness of a wiring line film which is formed of NiCr on the beam 
104
 is 50 nm. The diaphragm 
105
 as a light receiving section is composed of a thin film 
107
 of vanadium oxide with the resistance of 20 k&OHgr; as a bolometer material and a protective insulating film 
106
 of silicon nitride with the thickness of 800 nm. A full reflection film 
108
 is formed on the surface of the readout circuit 
102
 through the protective insulating film.
When infrared rays 
109
 are incident on the diaphragm 
105
 in such a thermal separation structure, the infrared rays 
109
 are absorbed by the silicon nitride thin film 
106
. A part of the infrared rays 
109
 passes through the diaphragm 
105
 and then is reflected to the direction of the diaphragm 
105
 by the reflection film 
108
. Thus, the reflected infrared rays are absorbed once again by the silicon nitride thin film 
106
. In this way, the infrared rays are absorbed so that the temperature of the diaphragm 
105
 changes. The resistance of the bolometer thin film 
107
 changes through the change of the temperature, and is converted into a voltage change by the readout circuit. Thus, an infrared picture is obtained.
Also, as the infrared ray detecting device, a bolometer type noncooled infrared sensor array by H. Wada et al., (SPIE Vol. 3224, 1997, p40) is known. 
FIGS. 7 and 8
 show a thermal separation structure of a picture element of the bolometer type noncooled infrared sensor array. 
FIG. 3
 is a plan view showing the picture element, and 
FIG. 4
 is a sectional view of the picture element along a broken line shown by a point line of A
1
-A
2
-A
3
-A
4
-A
5
-A
6
-A
7
-A
8
-A
9
-A
10
. A diaphragm 
113
 is supported by two beams 
112
 to form an air gap between the diaphragm 
113
 and a silicon substrate 
111
 with a readout circuit. The structure material of the beam 
112
 is a protective insulating film 
114
 of silicon nitride, and a wiring line material 
115
 of the beam 
112
 is a Ti film having the thickness of 100 nm. The diaphragm 
113
 as a light receiving section is formed of a vanadium oxide thin film 
116
 with the sheet resistance of 10 to 30 k&OHgr;/sq as bolometer material, an protective insulating film 
117
 of silicon nitride with the thickness of 400 nm and an infrared absorption film 
118
 of TiN thin film with the thickness of 15 nm.
The wiring line 
115
 on the beam 
112
 is connected with the readout circuit in the silicon substrate 
111
 by wiring line plugs 
121
 through a contact 
120
 provided in a bank section 
119
. Also, a reflection film 
122
 of a WSi film with the thickness of 20 nm and a protective insulating film 
123
 are formed on the silicon substrate through a thermal oxidation film.
The distance between the reflection film 
122
 and the infrared absorption film 
118
 is adjusted to 1/(4n) of the wavelength of an infrared ray to be detected (n is effective refractive index). The infrared rays are absorbed by the infrared absorption film 
118
. A part of the infrared rays passes through the infrared absorption film 
118
, and then are reflected by the reflection film 
122
 to the direction of the diaphragm 
113
. In the diaphragm 
113
, the infrared rays interfere with each other so that a component of the infrared rays with the wavelength to be detected is absorbed by the infrared absorption film 
118
. Thus, change of the temperature of the diaphragm is caused. The resistance of the bolometer thin film 
116
 changes through the change of the temperature, and the change of the resistance is converted into a voltage change by the readout circuit. In this way, an infrared picture is obtained.
Also, as the infrared ray detecting device, a micro-bolometer array by Cunningham et al., (U.S. Pat. No. 5,688,699) is known. 
FIG. 5
 shows a thermal separation structure of a picture element of the micro-bolometer array. As shown in 
FIG. 5
, an epitaxial layer 
131
 is grown on a silicon substrate 
130
, and a readout circuit for the bolometer is formed in the epitaxial layer 
131
. A diaphragm 
133
 is provided above the epitaxial layer 
131
 and is supported by two beams 
132
 and 
132
′ to form an air gap between the diaphragm 
133
 and the epitaxial layer 
131
.
The structure material of the beam 
132
 or 
132
′ is silicon nitride 
134
, and a wiring line 
135
 on the beam 
132
 or 
132
′ is formed of a Cr film with the thickness of 10 nm and a Ni film with the thickness of 20 nm. The diaphragm 
133
 as a light receiving section is formed of a vanadium oxide thin film 
136
 of bolometer material with the sheet resistance of 15 to 30 k&OHgr;. Also, the diaphragm 
133
 is further composed of a protective insulating film 
137
 of silicon nitride with the thickness of 100 nm and an infrared absorption film of a gold thin film having the thickness of 10 nm. In 
FIG. 5
, the absorption film is not shown.
The diaphragm 
133
 and wiring line films are electrically connected by contact sections 
138
a 
and 
138
b 
formed of the bolometer material. Also, the wiring line films and the readout circuit in the epitaxial layer are electrically connected by a contact 
139
. Also, the epitaxial layer 
131
 is covered by a SiO
2 
protective insulating film 
140
 and a reflection film composed of a Pt film with the thickness of 50 nm and a Cr film with the thickness of 5 nm. In 
FIG. 5
, a reflection film is not shown.
The distance between the reflection film and the infrared absorption film is adjusted to ¼n of a detection wavelength (n: effective refractive index). The infrared rays absorbed by the infrared absorption film and the infrared rays passing through the infrared absorption film and then reflected by the reflection film to the direction of the diaphragm interfere with each other. As a result, the infrared rays with the detection wavelength are absorbed by the infrared absorption film, so that the temperature of the diaphragm changes. The resistance of the bolometer thin film changes through the change of the temperature, and the change of the resistance is converted into a voltage change by the readout circuit. In this way, an infrared picture is obtained.
Also, as the infrared ray detecting device, a pyroelectric-type array by Hanson et al., (SPIE vol. 3379, 1998, p60) is known. 
FIGS. 6 and 7
 are a thermal separation structure of a picture element of the pyroelectric type array. As shown in 
FIGS. 6 and 7
, a diaphragm 
152
 is supported by two beams 
151
 to form an air gap′ between the diaphragm 
152
 and a silicon substrate 
150
 with a readout circuit. The diaphragm 
152
 is composed of a lower electrode 
153
 of Pt/Ti, a pyroelectric thin film 
154
 of (Pb,La)(Zr,Ti)O
3 
with the thickness of 250 to 350 nm on the electrode 
153
 and an upper electrode 
155
 of a Nickel-Chrome thin film. One of the two beams 
151
 is composed of the lower electrode 
153
 and the pyroelectric thin film 
154
, and the other beam 
151
 is composed of the pyroelectric thin film 
154
 and the upper electrode 
155
. The thermal conduction of such a well known thermal separation structure of is determined b
Kawano Katsuya
Oda Naoki
Epps Georgia
Hasan M.
NEC Corporation
Scully Scott Murphy & Presser
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