Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...
Reexamination Certificate
2001-07-27
2002-05-14
Robinson, Allen J. (Department: 1616)
Drug, bio-affecting and body treating compositions
Designated organic active ingredient containing
Having -c-, wherein x is chalcogen, bonded directly to...
C514S357000
Reexamination Certificate
active
06387933
ABSTRACT:
This application is the national phase under 35 U.S.C. § 371 of PCT International Application No. PCT/JP99/00352 which has an International filing date of Jan. 27, 1999, which designated the United States of America and was not published in English.
TECHNICAL FIELD
The present invention relates to pesticidal compositions and pesticidal methods.
BACKGROUND ARTS
Pesticides for controlling various pests such as agricultural and forestry pests, ectoparasites of animals and insanitary pests have been developed, and organophosphorus compounds, carbamate compounds, pyrethroid compounds, insect growth regulating substances and so on have been utilized so far. In some cases of application, however, it cannot be said that they exhibit satisfactory effects.
The present invention provides pesticidal compositions and pesticidal methods which are very effective for controlling the pests in agricultural and forestry fields, and further effective for controlling ectoparasites of animals, insanitary pests and the other various pests.
DISCLOSURE OF THE INVENTION
The present invention solved the problems by a pesticidal composition comprising (E)-N
1
-[(6-chloro-3-pyridyl)methyl]-N
2
-cyano-N
1
-methylacetamidine and 4-phenoxyphenyl 2-(2-pyridyloxy)propyl ether as active ingredients and a pesticidal method comprising utilizing (E)-N
1
-[(6-chloro-3-pyridyl)methyl]-N
2
-cyano-N
1
-methylacetamidine and 4-phenoxyphenyl 2-(2-pyridyloxy)propyl ether together.
Namely, the present invention provides a pesticidal composition (hereinafter, referred to as the present pesticidal composition) comprising (E)-N
1
-[(6-chloro-3-pyridyl)methyl]-N
2
-cyano-N
1
-methylacetamidine (hereinafter, referred to as acetamiprid) and 4-phenoxyphenyl 2-(2-pyridyloxy)propyl ether (hereinafter, referred to as pyriproxyfen) as active ingredients and a pesticidal method (hereinafter, referred to as the present pesticidal method) comprising utilizing acetamiprid and pyriproxyfen together.
Acetamiprid used in the present pesticidal composition and the present pesticidal method is a compound described in U.S. Pat. No. 5,304,566 specification and pyriproxyfen is a compound described in U.S. Pat. No. 4,751,225 specification. These compounds can be produced according to the descriptions in these specifications. Further, acetamiprid or pyriproxyfen on the market can be used.
The combination of acetamiprid and pyriproxyfen produces a synergistic effect that is clearly larger than a sum of the sole effect of each compound as shown in the test examples described later.
In the present pesticidal composition and the present pesticidal method, acetamiprid and pyriproxyfen are combined and utilized in a ratio that can produce a synergistic effect. It is usually 0.01 to 10 parts by weight of pyriproxyfen, preferably 0.05 to 5 parts by weight based on 1 part by weight of acetamiprid.
The present pesticidal composition and the present pesticidal method can be applied for controlling various pests such as agricultural and forestry pests, ectoparasites of animals and insanitary pests. Examples of the pest include Hemipteran pests such as Delphacidae (planthoppers) [e.g.
Laodelphax striatellus
(small brown planthopper),
Nilaparvata lugens
(brown planthopper) and
Sogatella furcifera
(white-backed rice planthopper)], Deltocephalidae (leafhoppers) [e.g.
Nephotettix cincticeps
and
Nephotettix virescens
], Aphididae (aphids) [e.g.
Aphis gossypii
(cotton aphids),
Myzus persicae
(green peach aphid),
Aphis citricola, Lipaphis pserudobrassicae
(turnip aphid),
Nippolachnus piri, Toxoptera aurantii
(black citrus apid) and
Toxoptera citricidus
(brown citrus apid)], stink bugs [e.g.
Nezara antennata
(green stink bug),
Cletus punctiger, Riptortus clavetus
(bean bug) and
Plautia stali
(oriental stink bug)], Aleyrodidae (whiteflies) [e.g.
Trialeurodes vaporariorum
(greenhouse whitefly),
Bemisia tabaci
(sweetpotato whitefly) and
Bemisia argentifolli
(silverleaf whitefly)], scales, Tingidae (lace bugs) and Psyllidae (suckers); Lepidopteran pests such as Pyralidae [e.g.
Chilo suppressalis
(rice stem borer),
Cnaphalocrocis medinalis
(rice leafroller),
Ostrinia nubilalis
(European cornborer),
Parapediasia teterrella
(bluegrass webworm),
Notarcha derogata
(cotton leafroller) and
Plodia interpunctella
(Indian meal moth)], Noctuidae [e.g.
Spodoptera litura
(tobacco cutworm),
Pseudaletia separata
(rice armyworm),
Mamestra brassicae
(cabbage armyworm),
Agrotis ipsilon
(black cutworm), Trichoplusia spp., Heliothis spp. and Helicoverpa spp.], Pieridae [e.g.
Pieris rapae
], Tortricidae [e.g. Adoxophyes spp.,
Grapholita molesta
(oriental fruit moth) and
Cydia pomonella
], Carposinidae [e.g.
Carposina niponensis
(peach fruit moth)], Lyonetiidae [e.g. Lyonetia spp.], Lymantriidae [e.g. Lymantria spp. and Euproctis spp.], Yponameutidae [e.g.
Plutella xylostella
], Gelechiidae [e.g.
Pectinophora gossypiella
(pink bollworm)], Arctiidae (tiger moths) [e.g.
Hyphantria cunea
(fall webworm)] and Tineidae [e.g.
Tinea translucens
(casemaking clothes moth) and
Tineola bisselliella
(webbing clothes moth)]; Dipteran pests such as Culex spp. [e.g.
Culex pipiens pallens
and
Culex tritaeniorhynchus
], Aedes spp. [e.g.
Aedes albopictus
], Anopheles spp. [e.g.
Anopheles sinensis
], Chironomidae (midges), Ceratopogonidae (biting midges) [e.g.
Culicoides oxystoma
], Muscidae [e.g.
Musca domestica
(housefly),
Muscina stabulans
(false housefly),
Musca hervei
and
Musca bezzii
], Calliphoridae, Sarcophagidae, Fannia spp. (little house flies), Anthomyiidae [e.g.
Delia platura
(seedcorn maggot) and
Delia antiqua
(onion maggot)], Tephritidae (fruit flies), Drosophilidae (vinegar flies), Psychodidae (sand flies), Simuliidae (black flies) [e.g.
Simulium iwatens
], Tabanidae [e.g.
Tabanus chrysurus
], Stomoxyidae (stable flies) [e.g.
Haematobia irritans
] and Agromyzidae (leafminer flies); Coleopteran pests such as corn rootworms [e.g.
Diabrotica virgifera virgifera
(western corn rootworm) and
Diabrotica undecimpunctata howardi
(southern corn rootworm)], Scarabaeidae [e.g.
Anomala cuprea
and
Anomala rufocuprea
], Curculionidae (weevils) [e.g.
Sitophilus zeamais
(maize weevil),
Lissorhoptrus oryzophilus
(ricewater weevil),
Hypera pastica
(alfalfa weevil) and
Callosobruchuys chienensis
(adzuki bean weevil)], Tenebrionidae (darkling beetles) [e.g.
Tenebrio molitor
(yellow mealworm) and
Tribolium castaneum
(red flour beetle)], Chrysomelidae (leaf beetles) [e.g.
Aulacophora femoralis
(cucurbit leaf beetle),
Phyllotreta striolata
(striped flea beetle) and
Leptinotarsa decemlineata
(Colorado beetle)], Anobiidae, Epilachna spp. [e.g.
Epilachna vigintioctopunctata
], Lyctidae (powderpost beetles), Bostrychidae, Cerambycidae and
Paederus fuscipes
; Dictyopteran pests such as
Blattella germanica
(German cockroach),
Periplaneta fuliginosa
(smokybrown cockroach),
Periplaneta americana
(American cockroach),
Periplaneta brunnea
(brown cockroach) and
Blatta orientalis
; Thysanopteran pests such as
Thrips palmi, Thrips tabaci, Thrips hawaiiensis
(flower thrips),
Scirtothrips dorsalis
(yellow tea thrips),
Frankliniella intonsa
(flower thrips),
Frankiniella occidentalis
(western flower thrips) and
Ponticulothrips diospyrosi
; Hymenopteran pests such as Formicidae (ants), Vespidae (hornets), Bethylidae and Tenthredinidae (sawflies) [e.g.
Athalia japonica
(cabbage sawfly)]; Orthopteran pests such as Gryllotalpidae (mole crickets) and Acrididae (grasshoppers); Siphonapteran pests such as
Pulex irritans
(human flea),
Ctenocephalides felis
(cat flea) and
Ctenocephalides canis
(dog flea); Anopluran pests such as
Pediculus humanus corporis, Phthirus
Nakamura Satoshi
Sembo Satoshi
Robinson Allen J.
Sumitomo Chemical Company Limited
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