Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By isomerization
Reexamination Certificate
2000-02-24
2002-03-12
Dang, Thuan D. (Department: 1764)
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
By isomerization
C585S482000
Reexamination Certificate
active
06355853
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to catalytic hydrocarbon conversion, and more specifically a process for aromatics isomerization.
GENERAL BACKGROUND AND RELATED ART
The xylenes, para-xylene, meta-xylene and ortho-xylene, are important intermediates which find wide and varied application in chemical syntheses. Para-xylene upon oxidation yields terephthalic acid which is used in the manufacture of synthetic textile fibers and resins. Meta-xylene is used in the manufacture of plasticizers, azo dyes, wood preservers, etc. Ortho-xylene is feedstock for phthalic anhydride production.
Xylene isomers from catalytic reforming or other sources generally do not match demand proportions as chemical intermediates, and further comprise ethylbenzene which is difficult to separate or to convert. Para-xylene in particular is a major chemical intermediate with rapidly growing demand, but amounts to only 20-25% of a typical C
8
-aromatics stream. Adjustment of isomer ratio to demand can be effected by combining xylene-isomer recovery, such as adsorption for para-xylene recovery, with isomerization to yield an additional quantity of the desired isomer. Isomerization converts a non-equilibrium mixture of the xylene isomers which is lean in the desired xylene isomer to a mixture which approaches equilibrium concentrations.
Various catalysts and processes have been developed to effect xylene isomerization. In selecting appropriate technology, it is desirable to run the isomerization process as close to equilibrium as practical in order to maximize the para-xylene yield; however, associated with this is a greater cyclic C
8
loss due to side reactions. The approach to equilibrium that is used is an optimized compromise between high C
8
cyclic loss at high conversion (i.e. very close approach to equilibrium) and high utility costs due to the large recycle rate of unconverted C
8
aromatics.
Catalysts for isomerization of C
8
aromatics ordinarily are classified by the manner of processing ethylbenzene associated with the xylene isomers. Ethylbenzene is not easily isomerized to xylenes, but it normally is converted in the isomerization unit because separation from the xylenes by superfractionation or adsorption is very expensive. One approach is to react the ethylbenzene to form a xylene mixture via conversion to and reconversion from naphthenes in the presence of a solid acid catalyst with a hydrogenation-dehydrogenation function. An alternative widely used approach is to dealkylate ethylbenzene to form principally benzene while isomerizing xylenes to a near-equilibrium mixture. The former approach enhances xylene yield by forming xylenes from ethylbenzene, while the latter approach commonly results in higher ethylbenzene conversion, thus lowering the quantity of recycle to the para-xylene recovery unit and concomitant processing costs.
In the past twenty years or so, crystalline aluminosilicate zeolite-containing catalysts have become prominent for xylene isomerization. U.S. Pat. No. 3,856,872 (Morrison), for example, teaches xylene isomerization and ethylbenzene conversion with a catalyst containing ZSM-5, -12, or -21 zeolite. U.S. Pat. No. 4,626,609 (Shihabi) discloses conversion of xylene isomers using a catalyst comprising a composite which has been steamed at 200° to 500° C. U.S. Pat. No. 4,899,012 (Sachtler et al.) teaches the use of a catalyst containing lead, a Group VIII metal, a pentasil zeolite and an inorganic-oxide binder to isomerize xylenes and dealkylate ethylbenzene. Development efforts continue toward realizing economically attractive isomerization catalysts with a superior combination of activity, selectivity and stability.
SUMMARY OF THE INVENTION
A principal object of the present invention is to provide a novel isomerization process for alkylaromatic hydrocarbons. More specifically, this invention is directed to the processing of C
8
aromatics to increase the concentration of a desired xylene isomer.
This invention is based on the discovery that improved conversion of C
8
aromatics and selectivity for xylene isomerization can be obtained using a silica-bound zeolitic catalyst which has been prepared in a manner to achieve specified characteristics.
Accordingly, a broad embodiment of the invention is directed toward an alkylaromatics-isomerization process using a catalyst comprising a zeolitic aluminosilicate having a pore diameter of from about 5 to 8 Å, a platinum-group metal component and a silica binder. The process comprises isomerization preferably of a feedstock comprising a non-equilibrium mixture of xylenes and ethylbenzene at isomerization conditions to obtain a product having an increased para-xylene content relative to that of the feedstock. Relevant isomerization conditions comprise a temperature of from about 300° to 600° C., a pressure of from about 100 kPa to 5 MPa, a mass hourly space velocity of from about 0.5 to 100 hr
−1
. Operation at a temperature of between 370° to 500° C. at a mass hourly space velocity of from about 10 to 50 hr
−1
is especially favored. MFI-type zeolite is the favored zeolitic aluminosilicate, especially as contained in an oil-dropped spherical catalyst The catalyst has a low 4.6 torr water capacity of less than about 7 mass-%, and preferably between about 3 and about 5 mass-%. The platinum-group metal preferably comprises platinum in a low concentration of between 100 and 2000 mass-ppm, and more preferably between about 200 and 800 mass-ppm, of the catalyst. The finished catalyst optimally has a water capacity at 4.6 torr and 25° C. of no more than about 5.5 mass-%
These, as well as other objects and embodiments, will become evident from the following detailed description of the invention.
REFERENCES:
patent: 3856872 (1974-12-01), Morrison
patent: 4101598 (1978-07-01), Whittam et al.
patent: 4537866 (1985-08-01), Gilson
patent: 4626609 (1986-12-01), Shihabi
patent: 4724066 (1988-02-01), Kirker et al.
patent: 4727209 (1988-02-01), Chao
patent: 4899012 (1990-02-01), Sachtler et al.
Gurevich Sergey V.
Sharma Sanjay B.
Dang Thuan D.
Spears, Jr. John F.
Tolomei John G.
UOP LLC
LandOfFree
Selective xylenes isomerization and ethylbenzene conversion does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Selective xylenes isomerization and ethylbenzene conversion, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Selective xylenes isomerization and ethylbenzene conversion will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2825809