Novel N-(alkyl)-N-(2-haloethyl)-aminomethylphosphonic acids, a m

Details Novel N-(alkyl)-N-(2-haloethyl)-aminomethylphosphonic acids, a m Novel N-(alkyl)-N-(2-haloethyl)-aminomethylphosphonic acids, a m

1980-08-29

1981-10-27

Evans, Joseph E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

536 49, 162175, C07F 938

Patent

active

042972990

ABSTRACT:
Starch ether derivatives are prepared by reacting a starch base with N-(2-haloethyl)iminobis(methylene)diphosphonic acid or with a N-(alkyl)-N-(2-haloethyl)aminomethylphosphonic acid. The derivatives contain aminophosphonic acid groups (or their salts) as zwitterion substituents which consist of either one or two anionic methylene phosphonic acid groups bound to a cationic nitrogen. Their cationic or anionic characteristics may be increased by introducing suitable cationic or anionic groups either by simultaneous reaction with the aminophosphonic acid reagent or by consecutive reaction either prior to or subsequent to the aminophosphonic acid reaction. They are especially useful as pigment retention aids in paper making processes. The N-(alkyl)-N-(2-haloethyl)aminomethylphosphonic acids are new reagents prepared by reacting a N-(2-haloethyl)alkylamine hydrohalide (e.g. N-(2-chloroethyl)ethylamine hydrochloride or N-(2-chloroethyl)cyclohexylamine hydrochloride), phosphorous acid, formaldehyde, and aqueous hydrochloric acid at 110.degree. to 125.degree. C. for 1 to 6 hours.

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