Production of epoxides from lower alkane-1,2-diols

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07D30102

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042972876

ABSTRACT:
Epoxides, e.g., ethylene and propylene oxides, are prepared from lower alkane-1,2-diols by dehydrating the corresponding diol, in liquid phase, under at least atmospheric pressure, and in the presence of at least one high-boiling organic carboxylic acid and at least one alkali metal or alkaline earth metal carboxylate.

REFERENCES:
patent: 4158008 (1979-06-01), Weitz et al.
H. R. Ansari et al., Tetrahedron Letters No. 35 (1975) pp. 3085-3086.
Chemical Abstracts, vol. 81 (1974) 135930w.

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