Optically active 3-substituted cyclooctene bicyclo-[6.0.3.]-unde

Details Optically active 3-substituted cyclooctene bicyclo-[6.0.3.]-unde Optically active 3-substituted cyclooctene bicyclo-[6.0.3.]-unde

1976-01-14

1978-07-04

O'Keefe, Veronica

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260666PY, C07C 300

Patent

active

040988341

ABSTRACT:
Optically active compounds are prepared from optically inactive unsaturated hydrocarbons by reacting at least one unsaturated hydrocarbon in the presence of a catalyst prepared by combining a nickel compound, a Lewis acid and an optically active phosphine of the general formula

REFERENCES:
chem. Ab. 81:119460n, 1974 [B. Adler et al., J. Prakt Chem. 316(3), 449-462 (Ger.) 1974].
Chem. Ab. 82:72559e, 1975 [J. Begenctak, J. Prakt. Chem. 316(6) 952-962 (Ger.) 1974].
Chem. Ab. 83:146711t, 1975 [Peter F. Boyle et al., J. Org. Chem. 40(18), 2682-2684, 1975].
Chem. Ab. 84:4057f, 1976 [George E. Greaur et al., Aust. J. Chem., 28(10), pp. 2227-2254, 1975].
Chem. Ab. 84 Index Bicyclo[7.2.0.9 Unde-4-eve, p. 10008c8.
Paul Karrer, Organic Chemistry, Elsevier Publishing Co. Inc., 4th Ed. 1950.

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