Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-12-22
1978-07-04
Siegel, A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2604495, C07C 2706
Patent
active
040988090
ABSTRACT:
Dimethyl ether is prepared by feeding a mixture of CO, CO.sub.2 and H.sub.2, wherein the quantity of CO is in excess of the stoichiometric value, to a reactor containing a methyl alcohol synthesis catalyst, such as a copper base or chrome-zinc base catalyst, and a methyl alcohol dehydration catalyst, such as alumina, whereby methyl alcohol is formed as an intermediate product which is transformed into dimethyl ether in the same reactor at a temperature in the range of 220.degree. to 400.degree. C and a pressure in the range of 30 to 500 kg/cm.sup.2.
REFERENCES:
patent: 3894102 (1975-07-01), Chang et al.
Brown et al., "Industrial & Engineering Chem," vol. 21, No. 4 (1929), pp. 310-313.
Ipatieff, "Journal of the Amer. Chem. Soc.," vol. 67, (1945), pp. 2168-2172.
Siegel A.
Snamprogetti S.p.A.
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