Process for arylamine production

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

Reexamination Certificate

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Reexamination Certificate

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07402699

ABSTRACT:
A tertiary arylamine compound, such as N,N-diphenyl-4-aminobiphenyl, is formed by reacting an arylbromidem such as 4-bromobiphenyl, and an arylamine, such as diphenylamine, preferably in the presence of a palladium ligated catalyst.

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Michele C. Harris et al; “One-Pot Synthesis of Unsymmetrical Triarylamines from Aniline Precursors”;J. Org. Chem. 2000, 65, pp. 5327-5333.
J. Org. Chem. 1989; K. Sukata and T. Akagawa, (Poly(ethylene glycol)s and Their Dimethyl Ethers as Catalysts for the Reaction of Aryl Halides with Diphenylamine in the Presence of Potassium Hydroxide, Aug. 12, 1988, pp. 1476-1479.

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