Process for direct oxidation of propylene to propylene oxide...

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – And additional al or si containing component

Reexamination Certificate

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C502S066000, C502S074000, C423S713000

Reexamination Certificate

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07399726

ABSTRACT:
Large crystals of titanium silicalite or intergrowths of intergrown smaller crystals, having a mean particle size greater than 2 μm, have been found catalytically effective at commercially reasonable rates for the epoxidation of olefins in the presence of hydrogen peroxide. Crystals synthesized with a silica source having a low sodium content exhibit high levels of production and selectivity. The crystals have a low attrition rate and are easily filterable from a product stream.

REFERENCES:
patent: 3351635 (1967-11-01), Kollar
patent: 4367342 (1983-01-01), Wulff et al.
patent: 4410501 (1983-10-01), Taramasso et al.
patent: 4833260 (1989-05-01), Neri et al.
patent: 5263090 (1993-11-01), Hughes
patent: 5354875 (1994-10-01), Nemeth et al.
patent: 5401486 (1995-03-01), Mueller et al.
patent: 5500199 (1996-03-01), Bellussi et al.
patent: 5859265 (1999-01-01), Müller et al.
patent: 5972661 (1999-10-01), Kubera et al.
patent: 6005123 (1999-12-01), Dessau et al.
patent: 6008389 (1999-12-01), Grosch et al.
patent: 6106803 (2000-08-01), Hasenzahl et al.
patent: 1 011 375 (1997-10-01), None
patent: 196 00 709 (1997-07-01), None
patent: 0 100 118 (1983-07-01), None
patent: 0 543 247 (1992-11-01), None
patent: 0 638 362 (1995-02-01), None
patent: 0 893 158 (1998-06-01), None
patent: WO 97/47386 (1997-12-01), None
patent: WO 98/00413 (1998-01-01), None
patent: WO 01/72420 (2001-10-01), None
J.F. Bengoa et al., “Influence of TS-1 Structural Properties and Operation Conditions on Benzene Catalytic Oxidation with H2O2,” Microporous and Mesoporous Materials 24 (1998) 163-172.
C. Perego et al., “Production of Titanium Containing Molecular Sieves and Their Application in Catalysis,” Applied Catalysis A: General 221 (2001) 63-72.
W. Laufer et al., “Direct Oxidation of Propylene and Other Olefins on Precious Metal Containing Ti-Catalysts,” Applied Catalysis A: General 213 (2001) 163-171.
Gang Li et al., “Epoxidation of Propylene Using Supported Titanium Silicalite Catalysts,” Applied Catalysis A: General 236 (2002) 1-7.
M.G. Clerici et al., “Epoxidation of Lower Olefins with Hydrogen Peroxide and Titanium Silicalite,” Journal of Catalysis 140, 71-83 (1993).
J.R. Monnier, “The Direct Epoxidation of Higher Olefins Using Molecular Oxygen,” Applied Catalysis A: General 221 (2001) 73-91.
C. Qui et al., “Epoxidation of Propylene Over Gold Catalysts Supported on Non-Porous Silica,” Applied Catalysis A: General 218 (2001) 81-89.
R. Meiers et al., “Synthesis of Propylene Oxide from Propylene, Oxygen, and Hydrogen Catalyzed by Palladium- Platinum-Containing Titanium Silicalite,” Journal of Catalysis 176, 376-386 (1998) Article No. CA 982036.
W. Laufer et al., “Propylene Epoxidation with Hydrogen Peroxide Over Palladium Containing Titanium Silicalite,” Journal of Molecular Catalysis A: Chemical 141 (1999) 215-221.
G. Li et al., “Effect of Sodium Ions on Propylene Epoxidation Catalyzed by Titanium Silicalite,” Applied Catalysis A: General 218 (2001) 31-38.
English Abstract corresponding to BE 1011375 A6, 1997.
English Abstract corresponding to DE 19600709, 1997.
A. Van der Pol et al., “Oxidation of Linear Alcohols with Hydrogen Peroxide Over Titanium Silicate 1,” Schuit Institute of Catalysis, Eindhoven Univ. of Technology, Appl. Catal. A., 106 (1) 97-113 (1993).
H. Gao et al., “Preparation of TS-1 Zeolite Suitable for Catalyzing the Epoxidation of Propylene,” Shanghai Research Institute of Petrochemical Technology, Shanghai, Peoples Republic of China, Shiyou Xuebao, Shiyou Jiagong (2000) 16 (3), p. 39-84.
C. Dartt et al., “Synthesis and Physiochemical Properties of Zeolites Containing Framework Titanium,” California Institute of Technology, Pasadena, CA, Microporous Matter, 2 (5), p. 425-437 (1994).
English Abstract of Belgian Patent No. 1,001,038, 1989.
English Abstract of JP 4-352771, 1992.

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