Long life lithium batteries with stabilized electrodes

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C429S321000, C429S324000, C429S330000, C429S337000, C429S338000

Reexamination Certificate

active

07968235

ABSTRACT:
The present invention relates to non-aqueous electrolytes having stabilization additives and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, a first additive that is a substituted or unsubstituted organoamine, substituted or unsubstituted alkane, substituted or unsubstituted alkene, or substituted or unsubstituted aryl compound, and/or a second additive that is a metal(chelato)borate. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes, the new electrolytes provide batteries with improved calendar and cycle life.

REFERENCES:
patent: 4513143 (1985-04-01), Ng et al.
patent: 4857423 (1989-08-01), Abraham et al.
patent: 5487959 (1996-01-01), Koksbang
patent: 5709968 (1998-01-01), Shimizu
patent: 5731106 (1998-03-01), Tsutsumi et al.
patent: 5763119 (1998-06-01), Adachi
patent: 5824434 (1998-10-01), Kawakami et al.
patent: 5849432 (1998-12-01), Angell et al.
patent: 5858573 (1999-01-01), Abraham et al.
patent: 6004698 (1999-12-01), Richardson et al.
patent: 6045952 (2000-04-01), Kerr et al.
patent: 6074777 (2000-06-01), Reimers et al.
patent: 6207326 (2001-03-01), Kawakami et al.
patent: 6232021 (2001-05-01), Negoro
patent: 6291107 (2001-09-01), Shimizu
patent: 6387571 (2002-05-01), Lain et al.
patent: 6395423 (2002-05-01), Kawakami et al.
patent: 6506516 (2003-01-01), Wietelmann et al.
patent: 6780545 (2004-08-01), Birke-Salam et al.
patent: 6787268 (2004-09-01), Koike et al.
patent: 6841303 (2005-01-01), Park et al.
patent: 7097944 (2006-08-01), Murai et al.
patent: 7172834 (2007-02-01), Jow et al.
patent: 7588859 (2009-09-01), Oh et al.
patent: 2001/0033964 (2001-10-01), Heider et al.
patent: 2002/0039687 (2002-04-01), Barker et al.
patent: 2003/0091892 (2003-05-01), Watanabe et al.
patent: 2003/0118912 (2003-06-01), Watanabe et al.
patent: 2003/0190529 (2003-10-01), Kim et al.
patent: 2004/0013944 (2004-01-01), Lee et al.
patent: 2004/0028996 (2004-02-01), Hamamoto et al.
patent: 2004/0029017 (2004-02-01), Besenhard et al.
patent: 2004/0121239 (2004-06-01), Abe et al.
patent: 2004/0131934 (2004-07-01), Sugnaux et al.
patent: 2004/0151951 (2004-08-01), Hyung et al.
patent: 2004/0157126 (2004-08-01), Belharouak et al.
patent: 2004/0191633 (2004-09-01), Johnson et al.
patent: 2004/0214091 (2004-10-01), Lim et al.
patent: 2005/0106470 (2005-05-01), Yoon et al.
patent: 2005/0227143 (2005-10-01), Amine et al.
patent: 75000095 (1975-01-01), None
Komaba, S. et al., “2-Vinylpyridine as Film-forming Additve [sic] to Suppress the Degradation of Carbon Anode by Dissolved Manganese for E/LiMn2O4Rechargable Battery,”Chemistry Letters, 2002, No. 12, pp. 1236-1237; published by The Chemical Society of Japan.
Yoshio, M. et al., “Storage and cycling performance of Cr-modified spinel at elevated temperatures,”Journal of Power Sources, vol. 101, pp. 79-85, Aug. 29, 2001; published by Elsevier Science B.V.
Davidson, I. J. et al., “Rechargeable cathodes based on Li2CRxMn2-xO4,”Journal of Power Sources, vol. 54, pp. 205-208, 1995; published by Elsevier Science B.V.
Xu, K. et al., “Lithium Bis(oxalate)borate Stabilizes Graphite Anode in Propylene Carbonate,”Electrochemical and Solid-State Letters, vol. 5, No. 11, pp. A259-A262, 2002; published by The Electrochemical Society, Inc. Available electronically Sep. 10, 2002.
Kannan, A. M. et al., “Surface/Chemically Modified LiMn2O4Cathodes for Lithium-Ion Batteries,”Electrochemical and Solid-State Letters, vol. 5, No. 7, pp. A167-A169, 2002; published by The Electrochemical Society, Inc. Available electronically May 3, 2002.
Blyr, A. et al., “Self-Discharge of LiMn2O4/C Li-Ion Cells in Their Discharged State,” vol. 145, No. 1, pp. 194-209, Jan. 1998; published by The Electrochemical Society, Inc.
Amatucci, G. G. et al., “Failure Mechanism and Improvement of the Elevated Temperature Cycling of LiMn2O4Compounds Through the Use of the LiAlxMn2-xO4-zFzSolid Solution,”J. Electrochem. Soc., vol. 148, No. 2, pp. A171-A182, 2001; published by The Electrochemical Society, Inc.
Sigala, C. et al., “Influence of the Cr Content on the Electrochemical Behavior of the LiCryMn2-yO4(0≦ y≦ 1) Compounds,”J. Electrochem. Soc., vol. 148, No. 8, pp. A826-A832, 2001; published by The Electrochemical Society, Inc. Available electronically Jun. 25, 2001.
Xu, W. et al., “Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions,”Electrochemical and Solid-State Letters, vol. 4, No. 1, pp. El-E4, 2001; published by The Electrochemical Society, Inc.
Amatucci et al., “Failure Mechanism and Improvement of the Elevated Temperature Cycling of LiMn2O4Compounds Through the Use of LiAlxMn2-xO4-zFzSolid Solution”Journal of the Electrochemical Society, (2001), pp. A171-A182, vol. 148, No. 2, The Electrochemical Society, Inc.
Andersson et al., “Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mössbauer spectroscopy study”,Solid State Ionics, (2000), pp. 41-52, vol. 130, Elsevier Science B.V.
Chen et al., “Chemical Overcharge and Overdischarge Protection for Lithium-Ion Batteries”,Electrochemical and Solid-State Letters, (2005), pp. A59-A62, vol. 8, No. 1, The Electrochemical Society, Inc.
Chen et al., “Reducing Carbon in LiFePO4/C Composite Electrodes to Maximize Specific Energy, Volumetric Energy, and Tap Density”,Journal of The Electrochemical Society, (2002), pp. A1184-A1189, vol. 149, No. 9, The Electrochemical Society, Inc.
Chung et al., “Electronically conductive phosphor-olivines as lithium storage electrodes”,Nature Materials, Oct. 2002, pp. 123-128, vol. 1, Nature Publishing Group.
Franger et al., “Optimized Lithium Iron Phosphate for High-Rate Electrochemical Applications”,J. Electrochem. Soc., May 27, 2004, pp. A1024-A1027, vol. 151, No. 7, The Electrochemical Society, Inc.
Huang et al., “Approaching Theoretical Capacity of LiFePO4at Room Temperature at High Rates”,Electrochemical and Solid-State Letters, Aug. 20, 2001, pp. A170-A172, vol. 4, No. 10, The Electrochemical Society, Inc.
Kellomäki et al., “Processing and properties of two different poly(ortho esters)”Journal of Materials Science: Materials in Medicine, (2000), pp. 345-355, vol. 11, Kluwer Academic Publishers.
Lee et al., “Synthesis of a Series of Fluorinated Boronate Compounds and Their Use as Additives in Lithium Battery Electrolytes”,J. Electrochem. Soc.. (2004), pp. A1429-A1435, vol. 151, No. 9, The Electrochemical Society, Inc.
Padhi et al., “Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries”,J. Electrochem. Soc.. Apr. 1997, pp. 1188-1194, vol. 144, No. 4, The Electrochemical Society, Inc.
Ravet et al., “Electroactivity of natural and synthetic triphylite”,Journal of Power Sources, (2001), pp. 503-507, Elsevier Science B.V.
Yamada et al., “Optimized LiFePO4for Lithium Battery Cathodes”,J. Electrochem. Soc.. (2001), A224-A229, vol. 148, No. 3, The Electrochemical Society, Inc.
International Search Report for PCT Application No. PCT/US06/08664, dated Dec. 13, 2006.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Long life lithium batteries with stabilized electrodes does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Long life lithium batteries with stabilized electrodes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Long life lithium batteries with stabilized electrodes will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2745194

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.