Rendering polybenzimidazole solid materials more resistant to da

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 308DS, 260 326N, 260 37N, 260 4575B, 260 4575C, 260 4575F, C08K 322, C08K 330, C08K 534, C08K 536

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040481395

ABSTRACT:
A route is provided for the formation of a polybenzimidazole solid material having an enhanced resistance to undergo the usual color darkening upon exposure to light. A minor concentration of a finely divided pigment found capable of stabilizing the background color inherently manifest by the polybenzimidazole polymer is dispersed in a solution of the polybenzimidazole, and the solvent is removed to produce a polybenzimidazole solid having the pigment substantially uniformly distributed therein. The pigment utilized may be arsenic thioarsenate, copper phthalocyanine, anatase titanium dioxide, or mixtures thereof. Fibers, films, three-dimensional shaped articles, etc. may be formed from the color stabilized polybenzimidazole.

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