Silver- and vanadium-containing multimetal oxide and its use

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C549S248000, C562S408000

Reexamination Certificate

active

07956200

ABSTRACT:
A multimetal oxide of the formula Iin-line-formulae description="In-line Formulae" end="lead"?Aga-bMbV2Ox*cH2O,  Iin-line-formulae description="In-line Formulae" end="tail"?where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo,a is from 0.3 to 1.9 andb is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 andc is from 0 to 20 andx is a number determined by the valence and amount of elements different from oxygen in the formula I,which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å.Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

REFERENCES:
patent: 3012043 (1961-12-01), Dennis et al.
patent: 3394468 (1968-07-01), Zeller
patent: 3485876 (1969-12-01), van de Mond
patent: 3684741 (1972-08-01), Friedrichsen et al.
patent: 3799886 (1974-03-01), Felice et al.
patent: 3871445 (1975-03-01), Wanka et al.
patent: 4077984 (1978-03-01), Blechschmitt et al.
patent: 4137259 (1979-01-01), Van Geem et al.
patent: 4203906 (1980-05-01), Takada et al.
patent: 4284571 (1981-08-01), Sato et al.
patent: 4665200 (1987-05-01), Nakanishi et al.
patent: 4965151 (1990-10-01), Takada et al.
patent: 5136104 (1992-08-01), Saito et al.
patent: 5225574 (1993-07-01), Aichinger et al.
patent: 5677261 (1997-10-01), Tenten et al.
patent: 5695892 (1997-12-01), Leising et al.
patent: 5792719 (1998-08-01), Eberle et al.
patent: 6281378 (2001-08-01), Kishimoto et al.
patent: 6288273 (2001-09-01), Heidemann et al.
patent: 6700000 (2004-03-01), Heidemann et al.
patent: 12 94 951 (1970-01-01), None
patent: 12 80 756 (1970-04-01), None
patent: 17 69 998 (1972-02-01), None
patent: 21 06 796 (1972-08-01), None
patent: 22 01 528 (1972-11-01), None
patent: 25 46 268 (1977-04-01), None
patent: 28 30 765 (1980-01-01), None
patent: 29 48 163 (1980-06-01), None
patent: 40 13 051 (1991-07-01), None
patent: 197 05 326 (1998-08-01), None
patent: 198 23 262 (1999-12-01), None
patent: 0 163 231 (1985-12-01), None
patent: 0 256 352 (1988-02-01), None
patent: 0 286 448 (1988-10-01), None
patent: 0 447 267 (1991-09-01), None
patent: 0 714 700 (1996-06-01), None
patent: 0 856 490 (1996-08-01), None
patent: 0 744 214 (1996-11-01), None
patent: 1 164 316 (1969-09-01), None
patent: 44/029045 (1969-11-01), None
patent: 46/042883 (1971-12-01), None
patent: 2 088 567 (1997-08-01), None
patent: WO 98/37967 (1998-09-01), None
Towae et al., “Phthalic Acid and Derivatives: Phthalic Anhydride” Ullmann's Encyclopedia of Industrial Chemistry vol. A 20, pp. 181-211 (1992).
Wells, “Structural Inorganic Chemisstry” pp. 621-625 (1984).
Rao et al., “Transition Metal Oxides” pp. 176-179 (1995).
Gmelin, “Silber und Vanadium” Gmelin Handbook 61, 274-277 (1974).
Andreikov et al., “Catalytic Oxidation of Toluene” Perroi. Chem. 17(3), 155-158 (1977).
Andreikov et al., “Catalytic Propertied of Vanadium Oxide Compounds of Silver in the Oxidation of o-Xylene and Naphthalene” Kinet. Katal. 22(4), 963-968 (1981).
Andreikov et al., “Pulse Study of the Vapor Phase Oxidation of o-Xylene over Vanadium-Silver Oxide Catalysts” Kinet. Katal. 22(5), 1207-1213 (1981).
Jun et al., “Catalytic Oxidation of Cyclopentadiene over Supported Vanadium Peroxide-Silver Catalysts” 63, 267-278 (1990).
Casalot et al., “Sur quelques nouvelles phases non-stoechiométriques du système Ag2O-V2O5-VO2” Bull. Soc. Chim. FR 10, 3817-3820 (1967).
Znaidi et al., “Synthesis of Vanadium Bronzes MxV2O5Through Sol-Gel Processes” Mat. Res. Bull. 24, 1501-1514 (1989).
Zhang et al., “A Study of Catalytic Activity, Constituent, and Structure of V-Ag Catalyst for Selective Oxidation of Toluene to Benzaldehyde” J. Cat. 122229, 426-437 (1991).
Volkov et al., “Phase Compositions of the silver vanadium oxide Ag0.8V2O5-vanadium pentoxide-copper vanadium oxide (CuV2O5) system” Zh. Neorg. Khim. 33(7), 1833 (1988); CA 109:157307 (1988).
Noe et al., “Selective oxidation of non-cyclic unsaturated hydrocarbon” esp@cenet English language Abstract of document AJ.

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