Proton exchange membranes for fuel cell applications

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C526S250000, C526S252000, C526S253000, C526S254000

Reexamination Certificate

active

07897691

ABSTRACT:
A proton conductive graft polymer comprises at least a structure unit of a sulfonated polymer side chain covalently attached to a hydrophobic perfluorocyclobutane polymer main chain. The sulfonated condensation polymer side chain has a high local ion exchange capacity while the main polymer chain is substantially free of sulfonic acid group. A membrane made from the graft polymer can provide good mechanical properties and high proton conductivity at wide range of humidity and temperatures.

REFERENCES:
patent: 5021602 (1991-06-01), Clement et al.
patent: 5037917 (1991-08-01), Babb et al.
patent: 5066746 (1991-11-01), Clement et al.
patent: 5159037 (1992-10-01), Clement et al.
patent: 5159038 (1992-10-01), Babb et al.
patent: 5316871 (1994-05-01), Swathirajan et al.
patent: 5910378 (1999-06-01), Debe et al.
patent: 6124060 (2000-09-01), Akita et al.
patent: 6183668 (2001-02-01), Debe et al.
patent: 6277512 (2001-08-01), Hamrock et al.
patent: 6384167 (2002-05-01), DesMarteau et al.
patent: 6444343 (2002-09-01), Prakash et al.
patent: 6521381 (2003-02-01), Vyas et al.
patent: 6523699 (2003-02-01), Akita et al.
patent: 6559237 (2003-05-01), Mao et al.
patent: 6670065 (2003-12-01), Koyama et al.
patent: 6847518 (2005-01-01), Fukuda et al.
patent: 6875537 (2005-04-01), Tani et al.
patent: 6926984 (2005-08-01), Asano et al.
patent: 6933068 (2005-08-01), Asano et al.
patent: 6953653 (2005-10-01), Smith et al.
patent: 6986962 (2006-01-01), Oyanagi et al.
patent: 7001929 (2006-02-01), Goto et al.
patent: 7045241 (2006-05-01), Akita et al.
patent: 7094851 (2006-08-01), Wu et al.
patent: 2001/0018144 (2001-08-01), Watakabe et al.
patent: 2002/0014405 (2002-02-01), Arcella et al.
patent: 2003/0017379 (2003-01-01), Menashi
patent: 2003/0096149 (2003-05-01), Koyama et al.
patent: 2003/0180596 (2003-09-01), Yoshimura et al.
patent: 2004/0214058 (2004-10-01), Tada et al.
patent: 2004/0214065 (2004-10-01), Kanaoka et al.
patent: 2005/0014927 (2005-01-01), Akita
patent: 2005/0043487 (2005-02-01), Felix et al.
patent: 2005/0048342 (2005-03-01), Wakahoi et al.
patent: 2005/0053810 (2005-03-01), Kato et al.
patent: 2005/0058864 (2005-03-01), Goebel
patent: 2005/0064260 (2005-03-01), Otsuki et al.
patent: 2005/0100770 (2005-05-01), Sugawara et al.
patent: 2005/0106440 (2005-05-01), Komiya
patent: 2005/0116206 (2005-06-01), Kakuta et al.
patent: 2005/0130024 (2005-06-01), Otsuki et al.
patent: 2005/0142397 (2005-06-01), Wakahoi et al.
patent: 2005/0143530 (2005-06-01), Iwadate et al.
patent: 2005/0175886 (2005-08-01), Fukuda et al.
patent: 2005/0197467 (2005-09-01), Komiya et al.
patent: 2005/0227138 (2005-10-01), Fukuda et al.
patent: 2005/0233181 (2005-10-01), Wariishi et al.
patent: 2005/0260474 (2005-11-01), Asano et al.
patent: 2006/0019147 (2006-01-01), Fukuda et al.
patent: 2006/0127728 (2006-06-01), Otsuki et al.
patent: 2006/0177719 (2006-08-01), Fuller et al.
patent: 2007/0042242 (2007-02-01), Tada et al.
patent: 2007/0099054 (2007-05-01), Fuller et al.
patent: 2007/0141237 (2007-06-01), Okiyama et al.
patent: 2008/0027152 (2008-01-01), Maier et al.
patent: 2009/0278083 (2009-11-01), Fuller et al.
patent: 2003535929 (2003-12-01), None
patent: 2005129298 (2005-05-01), None
patent: 2005166557 (2005-06-01), None
patent: 2005179380 (2005-07-01), None
patent: 2009249487 (2008-04-01), None
patent: 2009249487 (2009-10-01), None
patent: 20041051776 (2004-06-01), None
patent: 20071052954 (2007-05-01), None
Budy, S.M. et al., “Facile preparation of fluorovinylene aryl ether telechelic polymers with dual functionality for thermal chain extension and tandem crossliking,” Chem. Commun. 2006, pp. 4844-4846, 2006.
Li, Z. et al., A Novel Bisphenol Monomer with Grafting Capability and the Resulting Poly(arylene ether sulfone)s, Macromolecules 2006, 39, pp. 6990-6996.
Matsumura, S. et al., Iononners for Proton Exchange Membrane Fuel Cells with Sulfonic Acid Groups on the End Groups: Novel Branched Poly(eteher-ketone)s, Macromolecules 2008, 41, pp. 281-284.
Smith, D.W. et al., “Perfluorocyclobutane Aromatic Polyethers. Synthesis and Characterization of New Siloxane-Containing Fluoropolymers,” Macromolecules 1996, v. 29, pp. 852-860.
Smith, D.W. et al., “Perfluorocyclobutane (PFCB) polyaryl ethers: versatile coatings material,” J. of Fluorine Chem., v. 104, pp. 109-117 (2000).
Souzy, R. et al., “Functional fluoropolymers for fuel cell membranes,” Solid State Ionics, v. 176, pp. 2839-2848 (2005).
Souzy, R. et al., “Functional fluoropolymers for fuel cell membranes,” Prog. Polm. Sci. 30, 2005, pp. 644-687.
Ford, L.A. et al., “New Aromatic Perfluorovinyl Ether Monomers Containing the Sulfonimide Acid Functionality,” Polymeric Materials Science & Eng., v. 83, 2000, pp. 10-11 (American Chemical Society).
Souzy, R. et al., “Synthesis and (co)polymerization of monofluoro, difluoro, trifluorostyrene and ((trifluorovinyl)oxy) benzene,” Prog. Polm. Sci. 29 (2004), pp. 75-106.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Proton exchange membranes for fuel cell applications does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Proton exchange membranes for fuel cell applications, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Proton exchange membranes for fuel cell applications will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2723019

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.