Preparation of novel homo- and copolymers using atom transfer ra

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 90, 526135, 526145, 526146, 526147, 525168, 525243, 525245, 525247, 525255, 525258, 525259, 525261, 525269, C08F 444, C08F 400

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061628824

ABSTRACT:
The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.

REFERENCES:
patent: 3862978 (1975-01-01), Decker et al.
patent: 4145486 (1979-03-01), Haag et al.
patent: 5169914 (1992-12-01), Kaszas et al.
patent: 5405913 (1995-04-01), Harwood et al.
patent: 5451647 (1995-09-01), Faust et al.
patent: 5708102 (1998-01-01), Fryd et al.
patent: 5763548 (1998-06-01), Maty Jaszewski et al.
patent: 5767210 (1998-06-01), Lecomte et al.
patent: 5773538 (1998-06-01), Feiring
patent: 5789487 (1998-08-01), Maty Jaszewski et al.
patent: 5807937 (1998-09-01), Maty Jaszewski et al.
patent: 5811500 (1998-09-01), Dubois et al.
patent: 5854364 (1998-12-01), Senninger et al.
Kato et al, "Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris (Triphenylphospine)Ruthenium(II)Methylaluminum . . .", Macromolecules 1995, 28, 1721-1723.
T. E. Patten et al, "Polymers with very Low Polydispersities from Atom Transfer Radical Polymerization", Science, vol. 272, pp. 866-868, May 10, 1996.
V. Percec et al, "Self-Regulated Phase Transfer of Cu.sub.2 o/bpy, Cu(0)/bpy, and Cu.sub.2 o/cu(0)/bpy Catalyzed "Living" Radical Polymerization Initiated with Sulfonyl Chlorides", Macromolecules, vol. 31, No. 12, pp. 4053-4056, 1998.
A. Orochov et al, "Redox-Transfer, Part VI, Determination of Hammet's O-Constant for the Oxidation of Cuprous Chloride by Aromatic Sulphonyl Chlorides", J. Chem. Soc. (B), pp. 255-259.
M. Asscher et al, "Chlorine-Activation by Redox-Transfer, Part IV. The Addition of Sulphonyl Chlorides to Vinylic Monomers and Other Olefins", Asscher and Vofsi, pp. 4962-4971.
N. Kamigata et al, "Novel Perfluoroalkylation of Alkenes with Perfluoroalkanesulphonyl Chlorides Catalysed by a Ruthenium (II) Complex", J. Chem. Soc. Perkin Trans, pp. 627-633, 1991.
V. Percec et al, Living Radical Polymerization of Styrene Initiated by Arenesulfonyl Chlorides and Cu.sup.1 (bpy).sub.n C1, Macromolecules, vol. 28, No. 23, pp. 7970-7972, 1995.
V. Percec et al, "Metal-Catalyzed Living Radical Polymerization of Styrene Initiated with Arenesulfonyl Chlorides. From Heterogeneous to Homogeneous Catalysis", Macromolecules, vol. 29, No. 10, pp. 3665-3668, 1996.
Chemical Abstracts, vol. 85, 1976, pp. 20.
O. W. Webster, "Living Polymerization Methods", Science, vol. 25, Feb. 22, pp. 887-893, 1991.
S. Coca et al, "Polymerization of Acrylates by Atom Transfer Radical Polymerization. Homopolymerization of 2-Hydroxyethyl Acrylate", Journal of Polymer Science: Part A: Polymer Chemistry. vol. 36, pp. 1417-1424, 1998.
C. Granel et al "Controlled Radical Polymerization of Methacrylic Monomers in the Presence of Bis(ortho-chelated) Arylnickel(II) cCmplex and Different Activated Alkyl Halides", Macromolecules, vol. 29, No. 27, pp. 8576-8582, 1996.
K. Matyjaszewski et al, "Zerovalent Metals in Controlled/"Living" Radical Polymerization", Macromolecules. vol 30, No. 23, pp. 7348-7350, 1997.
C. Marestin et al, "Nitroxide Mediated Living Radical Polymerization of Styrene in Emulsion", Macromolecules, vol. 31, No. 12, pp. 4041-4044, 1998.
J. Xia et al, "Controlled/"Living" Radical Polymerization. Homogeneous Reverse Atom Transfer Radical Polymerization Using AIBN as the Initiator", Macromolecules, vol. 30, No. 25, pp. 7692-7696, 1997.
S. A.F. Bon et al, "Controlled Radical Polymerization in Emulsion", Macromolecules, vol. 30, No. 2, pp. 324-326, 1997.
Macromolecules"Evidence for Living Radical Polymerization of Methyl Methacrylate with Ruthenium Complex: Effects of Protic and Radical Compounds and Reinitiation from the Recovered Polymers," T. Nishikawa et al., vol. 30, No. 8, 1997, pp. 2244-2248, 1997.
T. Makino et al, "Controlled Atom Transfer Radical Polymerizations of Methyl Methacrylate under Micellar Conditions", pp. 288-289.
"Controlled "Living" Emulsion Polymerization of Methyl Methacrylate by Atom Transfer Radical Polymerization", pp. 90-134, (Part 2 of "AAP" Documents Above).
J.S. Wang et al, "Controlled Sequential and Random Radical Copolymerization of Styrene and Butyl Acrylate" Polym. Prepr. (ACS) 36(1), 1995, 465.
Takayuki OTSU et al, "Synthesis, Reactivity, And Role of Vinylbenzyl N, N-Diethyldithiocarbamate as a Monomer-Iniferter In Radical Polymerization", Macromolecules, vol. 19, No. 2, pp. 287-290, 1986.

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