Steam electrolysis

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Preparing nonmetal element

Reexamination Certificate

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Details

C205S628000, C205S629000, C204S252000, C204S262000, C204S263000, C204S266000

Reexamination Certificate

active

07906006

ABSTRACT:
The present invention relates to a method of producing hydrogen comprising: contacting steam (20) with a proton conducting membrane (7) supported on a porous redox stable substrate (8), through said substrate (8). The membrane (7) is non-permeable to molecular gas and to oxide ions. A DC voltage is applied across an anode (15) coupled to the substrate side of the membrane and a cathode (9, 11) coupled to its other side so as to dissociate at least part of the steam (20), into protonic hydrogen and oxygen at said anode (15). The protonic hydrogen passes through the membrane and forms molecular hydrogen (23) at the cathode (9, 11).

REFERENCES:
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patent: 0 472 922 (1992-03-01), None
International Search Report for corres. PCT/GB2005/001169 completed Jul. 19, 2005 by G. Hammerstein of the EPO.
Iwahara H: “Technological Challenges in the Application of Proton Conducting Ceramics”; Solid State Ionics, North Holland Pub. Company, Amsterdam, NL, vol. 77, Apr. 1995, pp. 289-298, XP004050460, ISSN: 0167-2738; paragraph 03.5.
Schneller, T et al: “Chemcial Solution Deposition Prepared Dense Proton Conducting Y-Doped BaZr03 Thin Films for SCFC and Sensor Devices”; Solid State Ionics, North Holland. Pub. Company, Amsterdam, NL, vol. 164, No. 3-4, Nov. 2003, pp. 131-136, XP004473999, ISSN: 0167-2738; p. 131, left-hand column, line 1-p. 131, right-hand column, line 5.
Iwahara H. et al: “Proton Conduction in Sintered Oxides Based on BACE03”; Journal of the Electrochemical Society, Electrochemical Society, Manchester, NH, US, vol. 135, No. 2, Feb. 1, 1988, pp. 529-533, XP000073186, ISSN: 0013-4651, “Experimental”; abstract.
Valkenberg S et al: “The Electrical Conductivity of the High Temperature Proton Conductor Ba3Cal.18Nb1.8209-delta”; Solid State Ionics, North Holland Pub. Company, Amsterdam, NL, vol. 97, No. 1-4, May 1, 1997, pp. 511-515, XP004126222, ISSN: 0167-2738; p. 511, left-hand column, line 1-p. 512, left-hand column, line 13.

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