Photographic element and process utilizing metal complex color m

Radiation imagery chemistry: process – composition – or product th – Color imaging process – Color correcting

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430367, 430375, 430378, 430542, 430543, 430559, 430547, G03C 140, G03C 718

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active

045554773

ABSTRACT:
A process of obtaining highly stable color masking dyes comprises use of an element which has a support having thereon at least one silver halide emulsion layer having associated therewith an essentially colorless, immobile, ligand-releasing compound of the structure LIG-X. In this structure, X is a group which, as a function of silver halide development, is cleaved from LIG, and LIG is a ligand capable of complexing with metal ions while joined to X to form a color masking dye. A color masking dye is formed by developing the imagewise exposed areas of the described element with a developing agent to cleave LIG from X and washing substantially all of the cleaved LIG moieties in those areas out of the element, and treating the element with metal ions to form a masking dye complex with LIG-X in unexposed areas.

REFERENCES:
patent: 2449966 (1948-09-01), Hanson, Jr.
patent: 2533182 (1950-12-01), Sargent
patent: 4142891 (1979-03-01), Baigrie et al.
Research Disclosure, publication 17643, paragraph VII, Dec. 1978.
Schilt, Talanta, 13, pp. 895-902, (1966).

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