Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing
Reexamination Certificate
2011-05-31
2011-05-31
Sullivan, Daniel M (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Halogen containing
C570S136000, C570S159000
Reexamination Certificate
active
07951982
ABSTRACT:
Disclosed is a process for the preparation of fluorinated olefins. In preferred embodiments C3 olefins are produced by methods comprising contacting a compound of the Formula (I)in-line-formulae description="In-line Formulae" end="lead"?C(R1aR2bR3c) (I)in-line-formulae description="In-line Formulae" end="tail"?with a compound of Formula (II)in-line-formulae description="In-line Formulae" end="lead"?C(R1aR2bR3c)Cn(R1aR2bR3c) IIin-line-formulae description="In-line Formulae" end="tail"?wherein R1a, R2b, and R3care independently a hydrogen atom or a halogen selected from the group consisting of fluorine; chlorine, bromine and iodine, provided that the compound of formula I has at least three halogen substituents and that said at three halogen substituents comprise at least one fluorine; a, b and c are independently=0, 1, 2 or 3 and (a+b+c)=2 or 3; and n is 0 or 1, under conditions effective to produce at least one C3 fluoroolefin.
REFERENCES:
patent: 2931840 (1960-04-01), Marquis
patent: 2996555 (1961-08-01), Rausch et al.
patent: 3472826 (1969-10-01), Potts et al.
patent: 3659023 (1972-04-01), Regan
patent: 4086407 (1978-04-01), Fozzard
patent: 4650914 (1987-03-01), Woodard
patent: 4798818 (1989-01-01), Baizer et al.
patent: 4900874 (1990-02-01), Ihara et al.
patent: 5162594 (1992-11-01), Krespan
patent: 5532419 (1996-07-01), Van Der Puy et al.
patent: 5545777 (1996-08-01), Morikawa et al.
patent: 5574192 (1996-11-01), Van Der Puy et al.
patent: 5608126 (1997-03-01), Morikawa et al.
patent: 5679875 (1997-10-01), Aoyama et al.
patent: 5710382 (1998-01-01), Dunmead et al.
patent: 5969198 (1999-10-01), Thenappan et al.
patent: 5986151 (1999-11-01), Van Der Puy
patent: 6023004 (2000-02-01), Thenappan et al.
patent: 6031141 (2000-02-01), Malikarjuna et al.
patent: 6066769 (2000-05-01), Nappa et al.
patent: 6111150 (2000-08-01), Sakyu et al.
patent: 6124510 (2000-09-01), Elsheikh et al.
patent: 6369284 (2002-04-01), Nappa et al.
patent: 6521802 (2003-02-01), Takubo et al.
patent: 6548719 (2003-04-01), Nair et al.
patent: 6809226 (2004-10-01), Pennetreau et al.
patent: 6958424 (2005-10-01), Nair et al.
patent: 6977316 (2005-12-01), Mukhopadhyay et al.
patent: 7026520 (2006-04-01), Mukhopadhyay et al.
patent: 7026521 (2006-04-01), Mukhopadhyay et al.
patent: 7071367 (2006-07-01), Mukhopadhyay et al.
patent: 7132578 (2006-11-01), Mukhopadhyay et al.
patent: 7135601 (2006-11-01), Mukhopadhyay et al.
patent: 7189884 (2007-03-01), Mukhopadhyay et al.
patent: 7196236 (2007-03-01), Mukhopadhyay et al.
patent: 7345209 (2008-03-01), Mukhopadhyay et al.
patent: 7371904 (2008-05-01), Ma et al.
patent: 2003/0060670 (2003-03-01), Nair et al.
patent: 2004/0119047 (2004-06-01), Singh et al.
patent: 2005/0020862 (2005-01-01), Tung et al.
patent: 2005/0080302 (2005-04-01), Baker et al.
patent: 2005/0090698 (2005-04-01), Merkel et al.
patent: 2005/0171391 (2005-08-01), Janssens et al.
patent: 2007/0112228 (2007-05-01), Mukhopadhyay et al.
patent: 2007/0112229 (2007-05-01), Mukhopadhyay et al.
patent: 2007/0112230 (2007-05-01), Mukhopadhyay et al.
patent: 2007/0129580 (2007-06-01), Mukhopadhyay et al.
patent: 0522639 (1993-01-01), None
patent: 0644173 (1995-03-01), None
patent: 0729932 (1996-09-01), None
patent: 974571 (2000-01-01), None
patent: 844597 (1960-08-01), None
patent: 11140002 (1999-05-01), None
patent: 2000169404 (2000-06-01), None
patent: 2000178543 (2000-06-01), None
patent: 9008752 (1990-08-01), None
patent: 9504021 (1995-02-01), None
patent: 96/01797 (1996-01-01), None
patent: 98/42645 (1998-03-01), None
patent: 98/21171 (1998-05-01), None
patent: 99/48993 (1999-09-01), None
patent: 00/39242 (2000-07-01), None
patent: 01/07384 (2001-02-01), None
patent: 03027051 (2003-04-01), None
patent: 2005/012212 (2005-02-01), None
patent: 2005/042451 (2005-05-01), None
patent: 2005108332 (2005-11-01), None
patent: 2005108334 (2005-11-01), None
patent: 2007019355 (2007-02-01), None
Banks, et al., Journal of Fluorine Chemistry, vol. 82, Issue 2, pp. 171-174 (1997).
Database Beilstein, Beilstein Institute for Organic Chemistry, M. Van Der Puy: J. Fluorine Chemistry, vol. 81, No. 2, 1997, pp. 187-192 XP002424669.
Database Beilstein, Beilstein Institute for Organic Chemistry, Haszeldine, Steele: J. Chem. Soc. 1953, p. 1592, 1597, XP0022424670.
Database WPI Week 199812, AN 1998-126110, XP002427152, Derwent Publications Ltd., London, GB & JP 10 007605A (Central Glass Co Ltd) Jan. 13, 1998 abstract.
Dickson, R.S., Fluorcarbon-Aluminium Compounds, Aust. J. Chem., 1972, 25, 761-8.
Gambareto et al., “The Reaction of chlorine monofloride with unsaturated compounds”, 1976, XP00246119.
Henne, Albert L., et al., Chlorinated Derivatives of 2-Floropropane1J. American Chemical Society, Jul. 11, 1941: pp. 2692-2694, vol. 63.
Knunyants, I. L. et al. Reaction of Fluoro Olefins, Institute of Heteroorganic Compounds, Bulletin of the Academy of Sciences of USSR, Division of Chemical Sciences -ISSN 0568-5230, p. 1312-1317.
March, J. Advanced Organic Chemistry, 1997, pp. 631-636, McGraw-Hill International Book Company, XP002427150.
Vittorio Minanari, A Novel Systensis of Perhalogenated Alkenes, J. Org. Chem. 1992, 57, 5018-5019.
B.V. Kunshenko, et al., “Reaction of Organic Compounds With SF4-HF-Halogenating System,” Journal of Organic Chemistry of the USSR, vol. 28, No. 4 pp. 672-680, Apr. 1992. RU.
Robert P. Salmon et al., “Experimental Flow Tube Study on Pyrolysis of 2-Chloro-1,1,1-Trifluoroethane,” Article, Department of Chemical Engineering, Villanova University, XP-001120412, pp. 507-510 (1996). US.
Database Belstein XP-002426121 (1951, 1952, 1998).
R.N. Haszeldine et al., “Free-radical Additions to Unsaturated Systems. Part XVII. Reaction of Trifluoroiodomethane with Mixtures of Ethylene and Vinyl Fluoride and of Ethylene and Propene,” J. Chem.Soc. (C), pp. 414-421 (1970).
J. Burdon et al., J. Fluorine Chemistry; EN; 40; pp. 283-318; XP-002424668. (1988).
M.P. Knunyants et al., “Reactions of Fluoro Olefins; Communication 13. Catalytic Hydrogenation of Periluoro Olefins,” Institute of Heteroorganic Compounds, Bulletin of the Academy of Sciences of the USSR, Division of Chemical Sciences, pp. 1312-1317; XP-000578879 (original article Mar. 3, 1959).
Johnson Robert C.
Merkel Daniel C.
Mukhopadhyay Sudip
Nair Haridasan K.
Puy Michael Van Der
Bradford Bruce
Honeywell International , Inc.
Sullivan Daniel M
Valenrod Yevegeny
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