Methods for preparing benzodithiophenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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Reexamination Certificate

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07956199

ABSTRACT:
Methods of adding substituents to a benzodithiophene are disclosed. A benzodithiophene is reacted with a reagent to directly add the substituent to the benzene core of the benzodithiophene. This method eliminates steps from prior process and eliminates the need for hydrogenation, allowing for a safer and more scaleable process. The resulting benzodithiophenes are suitable for use in semiconductor polymers and have no loss of performance.

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Pan et al., “Synthesis and Thin-Film Transistor Performance of Poly(4,8-didodecylbenzo[1,2-b:4,5-b′]dithiophene)”, Chem. Mater. 2006, 18, 3237-3241.
Beimling et al, “Synthesis of Benzo[1,2-b:4,5-b′]dithiophene and its 4,8-Dimethoxy and 4,8-Dimethyl Derivatives”, Chem. Ber. 119, 3198-3203 (1986).

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