Process for preparing solid polymers of norbornadiene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526144, 526160, 526161, 5261691, 526281, C08F 470, C08F 3206

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active

041003381

ABSTRACT:
Norbornadiene is catalytically polymerized to a solid white polymer in the presence of a catalytic system of nickel acetylacetonate or a nickel-phosphine complex and an alkyl aluminum chloride. The polymer can be used as a solid high energy fuel.

REFERENCES:
patent: 3140275 (1964-07-01), Spooncer
patent: 3192191 (1965-06-01), Lito et al.
patent: 3459825 (1969-08-01), Eberhardt et al.
Kennedy et al., Polymer, vol. 6, (1965), pp. 133-139.
Roller et al., Journal of Applied Polymer Sciences, vol. 17, (1973), pp. 2223-2233.
Schrauzer et al., Tetrahedron Letters, No. 8, (1970), pp. 543-545.

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