Preparation of beta-methyltetramethylene nortricyclane

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260666B, 260666A, 44 7R, C07C 1332

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active

041002164

ABSTRACT:
Norbornadiene and isoprene are catalytically codimerized to an olefinic codimer. Used is a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. The codimer upon hydrogenation forms .beta.-methyltetramethylene nortricyclane having utility as a diluent for a high energy hydrocarbon missile fuel.

REFERENCES:
patent: 2875256 (1959-02-01), Hyman
A. Greco et al., J. Org. Chem., vol. 35, No. 1, pp. 271-274, 1970.

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