Compositions: ceramic – Ceramic compositions – Refractory
Reexamination Certificate
1989-08-14
2001-10-30
Group, Karl (Department: 1755)
Compositions: ceramic
Ceramic compositions
Refractory
C501S100000, C501S127000, C428S294700, C428S375000, C428S378000, C428S396000
Reexamination Certificate
active
06309994
ABSTRACT:
TECHNICAL FIELD
The present invention relates to ceramic matrix composites having an aluminum phosphate bonded matrix. More particularly, the invention is directed to fiber reinforced aluminum phosphate bonded composites which exhibit high strength at temperatures up to approximately 1370° C.
BACKGROUND ART
Increasing demands in the aerospace industry are creating need for lightweight structural materials having increased strength-to-density and increased stiffness-to-density at high temperatures. As high temperature applications have exceeded 1200° C., increased attention has been directed to ceramics such as silicon carbide. However, the design problems associated with the brittle nature of ceramic materials and the difficulty of fabrication have presented severe obstacles.
Fiber-reinforced composite ceramic articles are receiving increasing interest in aerospace applications that require properties such as high chemical, wear and corrosion resistance and good structural integrity at high temperatures. Such reinforced ceramics are presently being considered as suitable structural materials for the fabrication of heat exchangers, turbocharger rotors, cylinders, bearings, and other components of heat engines. The incorporation of fiber reinforced ceramic matrix composites will permit heat engines run more efficiently at higher temperature than heretofore possible with similar components of metal.
Reinforcing ceramic oxides such as alumina (Al
2
O
3
) with silicon whiskers or fibers has produced some particularly useful fiber-reinforced composite ceramic materials. The function of the fibers in the matrix is to substantially increase the fracture toughness of the alumina and thereby inhibit deleterious crack formation and crack growth due to material fatigue.
U.S. Pat. No. 4,158,687 issued to Yajima et al discloses a technique for producing heat-resistant composite materials reinforced with continuous silicon carbide fibers. The composite material is formed by pressing and heating a powdery ceramic matrix having an average grain size of less than 100 microns and continuous silicon carbide fibers.
U.S. Pat. No. 4,358,500 issued to George et al discloses flame resistant insulating fabric compositions containing an inorganic bonding agent. The inorganic composition is prepared from a liquid bonding agent which is prepared from colloidal silica, monoaluminum phosphate (MAP) and aluminum chlorohydrate (ACH). The bonding agent is used on a porous fabric, such as fiberglass, to prepare fabric compositions that are flame and heat resistant and improved electrical insulating properties. U.S. Pat. No. 4,358,500 also discloses that a high temperature refractory coating may be formed by the addition of high temperature refractory material such as zirconium oxide powder (325 mesh) to the liquid bonding agent.
U.S. Pat. No. 3,730,744 issued to Yavorsky et al discloses an aluminum phosphate bonded refractory material suitable for use in casting refractory shapes and making a ceramic product. The composition contains aggregate ceramic particles which can be employed in the composition. Theses aggregate ceramic particles may include calcined clay, silicate aggregates, carbides silicates, nitrides, borides and some metal powders and grits. The aggregate ceramic particles are bonded together by an aluminum dihydrogen orthophosphate bonding solution which is prepared by the reaction of reactive aluminum orthophosphate Al(PO
4
), aluminum hydroxide or colloidal alumina with hot, concentrated phosphoric acid.
U.S. Pat. No. 4,440,865 issued to Salazar discloses refractory compositions based upon alumina or aluminum silicate which is chemically bound by aluminum phosphate. The composition is formed using both liquid aluminum phosphate and phosphoric acid to form a portion of the aluminum phosphate in situ.
U.S. Pat. No. 4,563,219 issued to George et al discloses an inorganic binder composition and refractory-binder coated fabric composition prepared therefrom. The inorganic binder solution employed in providing refractory coatings on fabric substrates is prepared from colloidal silica, monoaluminum phosphate (MAP) and aluminum chlorohydrate (ACH) and a catalyst of an alkyl tin halide. George discloses that the colloidal silica and water in the binder solution act as a moderator to delay the rapid exothermal chemical reaction that would normally occur when MAP is mixed with ACH.
U.S. Pat. No. 4,652,413 issued to Tiegs discloses a method for preparing silicon carbide whisker-reinforced alumina ceramic articles. The articles are formed by cold pressing a mixture of alumina powder and silicon carbide whiskers and then sintering at atmospheric pressure.
While silicon carbide reinforced ceramic composite materials have been shown to significantly increase the strength and fracture toughness over conventional ceramics, their strength, structural reliability and impact resistance have not met the demands of the high temperature applications for which they are being designed.
In addition to thermal performance problems, there are still problems that exists with the fabrication processes that are presently being used to make fiber reinforced ceramic matrix composites (CMC). Many of the current fabrication techniques are limited to the formation of fiber reinforced ceramic articles which possess relatively simple shapes and shallow thicknesses. For example, the hot pressing of ceramic particulate mixtures in die sets inhibits the fabrication of articles with relatively complex shapes such as turbocharger rotors, cylinders, bearings, and the like. In addition, the hot pressed ceramic reinforced composites require extensive machining and other finishing processes which considerably increase the expense of fabricating structural components of complex shapes.
Another fabrication technique that limits the shapes and thicknesses of fiber reinforced ceramic articles are those that utilize a binder solution containing a fugitive organic binder. The fugitive organic binder is used in the slurry matrix to improve the adhesion of the matrix to the fibers before sintering. The organic fugitive binders evolve gases that must be completely removed prior to sintering so that voids are not created in the sintered piece. As the cross sectional thickness of the piece increases, the time that the green ceramic article must remain in an oven at a low burn off temperature increases. In addition, as the size and cross sectional thickness of the article increases, the likelihood that the evolved gases will be trapped in the interior of the piece increases. Therefore, fabrication of pieces by techniques employing fugitive organic binders must employ an additional production step to insure the binders have burned off prior to sintering. This extra step may be quite lengthy and adds both labor costs and energy costs to the process.
Another disadvantage associated with above composite article manufacturing technique, which employs a fugitive organic binder, is that the organic fugitive binders can be a source of unwanted impurities in the resultant composite. The unwanted impurities often result in a lowering of the high temperature properties of the composite article.
Yet another disadvantage of current fabrication techniques is that the matrix does not uniformly surround the fibers. The nonuniformity of the green body results in a nonuniform sintered composite article which may contain voids. This problem can be alleviated to a certain extent by the use of binders solutions which carry ceramic particles further into the fabric (fibers) and into the interior of the article. However, often the fabric acts as a filter which removes ceramic particles from the binder solution. This results in the matrix having a composition which changes as one moves into the interior of the article. This problem of nonuniformity is further aggravated when forming complex and/or three-dimensional composite structures. The problems of nonuniformity can be overcome, however often the labor costs needed to insure compositional uniformity may make the cost of t
Bray Donald J.
Graddy, Jr. G. Edward
Marra Robert A.
Ray Siba P.
Aluminum Company of America
Gallo Chris
Group Karl
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