Selective aromatics disproportionation process

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By alkyl or aryl transfer between molecules – e.g.,...

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585470, C07C 522

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active

060639776

ABSTRACT:
An improved catalyst and process are disclosed for the selective disproportionation of toluene. The process uses a zeolitic catalyst which is oil-dropped in an aluminum phosphate binder and has an X-ray diffraction pattern showing characteristic intensities at specified Bragg angles. Optionally, the catalyst is selectively precoked prior to toluene disproportionation. The catalyst and process provide improved selectivity for the production of paraxylene.

REFERENCES:
patent: 4011276 (1977-03-01), Chu
patent: 4016219 (1977-04-01), Kaeding
patent: 4097543 (1978-06-01), Haag et al.
patent: 4182923 (1980-01-01), Chu
patent: 4629717 (1986-12-01), Chao
patent: 5169812 (1992-12-01), Kocal et al.

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