Mineral oils: processes and products – Products and compositions – Lubricating oils
Reexamination Certificate
1999-12-21
2001-08-21
Griffin, Walter D. (Department: 1764)
Mineral oils: processes and products
Products and compositions
Lubricating oils
C208S017000, C585S002000, C585S003000, C585S013000
Reexamination Certificate
active
06277269
ABSTRACT:
FIELD OF THE INVENTION
This invention is concerned with transporting heavy hydrocarbons through a pipeline. More particularly, the present invention relates to improvements in modifying the density and viscosity of bitumen to render it suitable for transporting it through a pipeline.
BACKGROUND OF THE INVENTION
With the decrease in the reserves of conventional crude oils, there is increasing use in petroleum refineries of heavy hydrocarbons such as those extracted from oil sands. These heavy hydrocarbons typically are geographically located in regions remote from refineries that can process them. Consequently, the hydrocarbons need to be transported to a refinery, most usually through a pipeline.
Presently the most convenient method for pipelining heavy hydrocarbons is by mixing the hydrocarbon with a diluent such as natural gas condensate to lower the viscosity and density of the hydrocarbon to render it suitable for pipelining. Experience has shown, however, that in order to meet the pipeline viscosity specifications, more diluent is used than is necessary to meet the density specifications. Moreover, there is growing concern that the supply of natural gas condensate may not keep pace with the continuing growth in use of such heavy hydrocarbons.
An alternate approach to modifying the viscosity and density of heavy hydrocarbons to a range suitable for pipelining involves subjecting the hydrocarbon to “partial upgrading” by hydroconversion, especially slurry hydroprocessing. By “partial upgrading” is meant to subject the hydrocarbon to hydroprocessing under conditions and for a time sufficient to reduce the viscosity and density to pipeline specifications. Partial upgrading, however, reduces the bitumen viscosity to a greater extent than the API gravity so that at the target density the viscosity of the product is significantly lower than that which is required. Additionally, depending upon the level of conversion, among other factors, phase separation of asphaltenes may occur.
Thus, there remains a need for modifying the viscosity and density of heavy hydrocarbons which does not result in asphaltene phase separation.
Additionally, there remains a need for an improved method for rendering heavy hydrocarbons pipelineable while using reduced amounts of diluent.
SUMMARY OF THE INVENTION
Accordingly, in one embodiment of this invention, there is provided an improvement in modifying a heavy hydrocarbon suitable for pipelining comprising:
subjecting the hydrocarbon to hydroconversion under conditions and for a time sufficient to provide a modified hydrocarbon having a viscosity of in the range of about 60 to 250 cP at 40° C. and
adding a diluent to the modified hydrocarbon in an amount sufficient to provide a mixture having an API gravity of at least about 19° at 15° C. and a viscosity at 40° C. of about 35 to about 60 cP, and preferably about 40 to about 50 cP.
In another embodiment a pipelineable mixture is provided which comprises a major amount of an oil having a viscosity at 40° C. in the range of about 60 to 250 cP and an API gravity at 15° C. in the range of about 15° to 17° and a diluent selected from the group consisting of naphtha and natural gas condensates in an amount sufficient whereby the mixture of oil and diluent has an API gravity at 15° C. of at least 19°.
DETAILED DESCRIPTION OF THE INVENTION
The heavy hydrocarbon material suitable for use in the practice of the present invention are those which contain a substantial position, i.e., greater than 50 vol. % of material boiling above 525° C., equivalent atmospheric boiling point. Indeed, of particular interest are the heavy hydrocarbon oils extracted from oil sands, most particularly Athabasca and Cold Lake oil sands. Typically, such heavy hydrocarbons at 40° C. have a viscosity exceeding 5,000 centipoise and an API gravity at 15° C. of less than about 10.5°.
According to this invention, the heavy hydrocarbon is first subjected to a hydroconversion process, i.e., the heavy hydrocarbon is contacted with hydrogen and a catalyst under pressure and temperature conditions sufficient to lower the viscosity of the hydrocarbon to the range of about 60 to about 250 cP at 40° C. Preferably the hydroconversion is conducted as a slurry at temperatures ranging between about 400° C. to about 450° C. and hydrogen partial pressures of about 700 psig to about 1500 psig.
Any hydroconversion catalyst may be used. Examples of a suitable catalyst employed in the hydroconversion are a molybdenum containing catalyst such as the phosphomolybdic acid catalyst disclosed in U.S. Pat. No. 5,620,591 and incorporated herein by reference or fly ash derived from bitumen coke. Typically, the catalyst is added to the heavy hydrocarbon in the range of about 100 ppm to about 7 wt. % based on the weight of heavy hydrocarbon. When the catalyst is a phosphomolybdic acid catalyst preferably it is added in the range of about 150 to about 500 ppm whereas when fly ash is used preferably it is used in the range of about 0.5 to about 5 wt. %.
After being converted under the foregoing conditions, the viscosity of the product oil is in the range of about 60 to 250 cP at 40°, the API gravity at 15° C. typically will be in the range of about 15° to 17°, which is not suitable for pipelining.
Next the API gravity of product oil is adjusted to 19° at 15° C. by adding sufficient diluent to the product oil. Typical diluents include naphtha and natural gas condensates. This also results in a blended product having a viscosity in the range of 35 to about 60 cP at 40° C. whereby the blended product is suitable for pipelining.
In an optional embodiment the catalyst used in the partial hydroconversion step may be removed from the product oil before adding diluent to adjust the oil API density.
As will be readily appreciated, adding diluent to a bitumen to render it pipelineable typically results in overtreatment from the standpoint of density. Conversely, subjecting a bitumen to hydroconversion to render it pipelineable results in over treatment from the standpoint of viscosity. The partial conversion and dilution process of the present invention provides a unique method for rendering a bitumen pipelineable while using significantly lower amounts of diluent than if only diluent were used while avoiding potential asphaltene phase separation that typically occurs if only hydroconversions were used.
REFERENCES:
patent: 3527692 (1970-09-01), Titus
patent: 4485004 (1984-11-01), Fisher et al.
patent: 4637871 (1987-01-01), Bearden, Jr. et al.
patent: 4666457 (1987-05-01), Hayes et al.
patent: 4933067 (1990-06-01), Rankel
patent: 5236577 (1993-08-01), Tipman et al.
patent: 5620591 (1997-04-01), Poole et al.
patent: 5622616 (1997-04-01), Porter et al.
Chakrabarty Tapan
Ghosh Mainak
MacLeod John Brenton
Myers Ronald Damian
Allocca Joseph J.
ExxonMobil Research and Engineering Company
Griffin Walter D.
Nguyen Tam M.
LandOfFree
Producing pipelineable bitumen does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Producing pipelineable bitumen, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Producing pipelineable bitumen will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2549784