Process for the preparation of 1,4-dialkylbut-2-ene-1,4-diones

Details Process for the preparation of 1,4-dialkylbut-2-ene-1,4-diones Process for the preparation of 1,4-dialkylbut-2-ene-1,4-diones

1980-11-17

1982-07-20

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C 4557

Patent

active

043407641

ABSTRACT:
1,4-Dialkylbut-2-ene-1,4-diones are obtained by oxidizing a 2,5-dialkylfuran with an aqueous solution of an inorganic hypochlorite at a pH from 7 to 10.

REFERENCES:
patent: 3931270 (1976-01-01), Evers et al.
patent: 3981920 (1976-09-01), Buchi
patent: 4082717 (1978-04-01), Brennan et al.
Held et al., Biochem & Biophys. Res. Comm., vol. 81, #3, pp. 878-885 (1978).
J.A.C.S., vol. 86, pp. 3879-3880, 1964, Foote et al.
Adam et al., J.A.C.S., vol. 102, pp. 404-406. (1980).
Koch et al., Chem. Ber., pp. 1984-1990 (1966).
Novilskii et al., Chem. Abst, vol. 59, #11394f (1963).
Brown et al., Can. J. Chem, vol. 35, p. 236, (1957).
Australian, J. of Chem., vol. 26, p. 2671 (1973).

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