Preparation of phosphonium phenoxide salts

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

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C07F 954

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043407617

ABSTRACT:
A tetrahydrocarbylphosphonium phenoxide salt is prepared by reacting a tetrahydrocarbylphosphonium halide salt with an alkali metal or ammonium hydroxide in a liquid reaction medium in the presence of at least an equivalent amount of a phenol. This method of preparation is especially effective where the hydroxide salt of the tetrahydrocarbylphosphonium is unstable. For example, benzyltriphenylphosphonium salt of bisphenol A complexed with bisphenol A is prepared by adding 1 equivalent of sodium hydroxide to a methanol solution containing 1 equivalent of benzyltriphenylphosphonium bromide and 2 equivalents of bisphenol A at 30.degree. C.

REFERENCES:
patent: 2102103 (1937-12-01), Urbain et al.
patent: 3325546 (1967-06-01), Harp
patent: 4093650 (1978-06-01), Doorakian et al.
Schindlbauer, Ber. 96 2109 (1963).

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