Optical: systems and elements – Optical frequency converter – Harmonic generator
Reexamination Certificate
1998-11-24
2001-04-10
Lee, John D. (Department: 2874)
Optical: systems and elements
Optical frequency converter
Harmonic generator
C359S326000
Reexamination Certificate
active
06215580
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to a wavelength converting technology and, more particularly, to a wavelength converter for laser light and a method for varying the wavelength of laser light.
DESCRIPTION OF THE RELATED ART
The laser light has found a wide variety of application such as, for example, semiconductor device fabrication technologies and a medical equipment. These applications require short-wavelength laser light, and research and development efforts have been made on a wavelength converter or a frequency converter for obtaining short-wavelength laser light.
While a wavelength converter is converting the wavelength of incident laser light, the wavelength converter generates heat due to various kinds of absorption such as, for example, two-photon absorption. If the wavelength of the incident light to be converted is close to absorption edge, the transmittance is small, and part of the incident light is absorbed by the wavelength converter. The heat is undesirable for the wavelength converter, because the heat is causative of decreasing the refractive index of the crystal of the wavelength converter. The decrease of the refractive index destroys the phase matching conditions and, accordingly, the wavelength converter decreases the power of the converted light. Thus, it is important to keep the temperature of the wavelength converter constant for stable wavelength conversion.
In order to control the temperature of the wavelength converter, the wavelength converter is accommodated in a holder formed of heat conductive material such as copper or aluminum, and an oven or a coolant keeps the holder in a temperature range through a feed-back control. Especially, when the wavelength converter is formed of material widely varied in refractive index with the temperature, it is necessary to strictly control the temperature within a narrow temperature range. In this instance, Japanese Patent Publication of Unexamined Application NO. 5-41557 proposes to embed the wavelength converter in a Peltier element, and the Peltier element keeps the wavelength converter in the narrow temperature range.
Although enlargement of crystal is effective against the decrease of the converting efficiency, the walk-off due to the double refraction characteristics of the enlarged crystal sets a limit on the converting efficiency, and the enlargement becomes invalid at a certain length. Japanese Patent Publication of Unexamined Application No. 50-150453 and U.S. Pat. No. 5,047,668 propose to use more than one element oriented in respective directions different at 180 degrees from a phase matching direction for compensating the walk-off.
In this situation, even though the short-wavelength laser light is required in the various technical fields, it is difficult to take out the short-wavelength laser light from the incident light. First, the dispersion of refractive index and the wavelength at the absorption edge are inherent in the material used for the wavelength converter, and they restricts the wavelength range of an optical harmonic to be generated. Even if a kind of material allows the wavelength converter to convert incident light to a wavelength close to the absorption edge, the dispersion of refractive index is so large around the absorption edge, and the wavelength converter suffers from low transmittance due to the absorption and the surface reflection loss. This means a low efficiency in the wavelength conversion. Second, the absorption during the wavelength conversion is causative of the temperature rise, and the temperature rise destroys the phase matching conditions, and a break-down is liable to take place due to the electron avalanche phenomenon. For this reason, the wavelength conversion around the absorption edge is not practical.
As described hereinbefore, there is a tendency that allowable refractive index range is narrowed when the temperature rises. Similar tendency is observed in the wavelength and the phase matching angle. For this reason, the wavelength conversion for short wavelength light is quite difficult. Moreover, a wavelength converter suffers from a large walk-off angle due to the double refraction, and the threshold of the dielectric breakdown is lowered. For this reason, it is difficult to enhance the wavelength conversion efficiency by prolonging the crystal length and increasing the energy density in the wavelength converter. Although the compensation of the walk-off angle is tried by using two elements, the compensation method is complicated, and a simple method is required for enhancing the converting efficiency in the wavelength conversion.
Moreover, when the wavelength conversion is carried out for ultraviolet light, the two-photon energy exceeds the band gap of the material used for the wavelength converter, and the wavelength converter generates heat at high efficiency due to the two-photon absorption. The heat varies the refractive index of the wavelength converter, and the phase matching conditions are destroyed. As a result, the wavelength converter decreases the output of the converted light. High power ultra violet light is required for industrial applications, and it is necessary to effectively control the temperature of the wavelength converter.
Light is transmitted through a portion where the heat is generated. The prior art temperature control system indirectly cools the portion, i.e., from the surrounding portion to the heat generating portion. The material used for the wavelength converter is small in heat conductivity, and the prior art temperature control system can not exactly control the temperature of the heat generating portion.
When 193 nm wavelength ultra violet light is generated from beta-BaB
2
O
4
, which has large nonlinear optical constant, the ultra violet light has the wavelength close to the absorption edge of the beta-BaB
2
O
4
, and the transmittance for the 193 nm wavelength light is of the order of 25 percent. This means that a large amount of heat is generated from the wavelength converter. The 193 nm wavelength light is Ar-F excimer laser light, and the Ar-F excimer laser light is expected to participate photo-lithography used for semiconductor devices in the next generation. However, the Ar-F excimer laser generator is low in electric-to-optic converting efficiency, and the manufacturer requires a suitable protective system against dangerous gas. For this reason, the Ar-F excimer laser generator occupies wide area, and the running cost is high. Thus, the manufacturer wants to replace the Ar-F excimer laser generator with a solid-state laser generator of beta-BaB
2
O
4
so as to reduce the installation cost, the running cost and the safety cost and improve the space utility of a clean room.
SUMMARY OF THE INVENTION
It is therefore an important object of the present invention to provide a wavelength converter, which achieves a high converting efficiency.
It is also an important object of the present invention to provide a method for converting the wavelength of light at a high converting efficiency.
The present inventor found that beta-BaB
2
O
4
shifted the absorption edge toward a short-wavelength region under low-temperature condition. The shift improved the transmittance around the absorption edge. The light was less absorbed, and the wavelength converter reduced the amount of heat generated in the wavelength conversion. In other words, the converting efficiency was improved. The present inventor proposed to cool the wavelength converter so as to take out short wavelength light from the wavelength converter at a high converting efficiency.
The present inventor further noticed that the walk-off angle was made invalid by using optical paths different at 180 degrees from one another with respect to an optical axis of a wavelength converting element. The present inventor increased the total length of the optical paths under the above optical conditions, and achieved a high converting efficiency.
In accordance with one aspect of the present invention, there is provided a wavelength converter comprising, a wavelength
Lee John D.
NEC Corporation
Young & Thompson
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