Semiconductor device having capacitor and method of...

Semiconductor device manufacturing: process – Making passive device – Stacked capacitor

Reexamination Certificate

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C438S396000, C438S653000, C438S652000, C438S253000, C438S239000

Reexamination Certificate

active

06242316

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device, and more particularly, to a semiconductor device having a capacitor and a method of fabricating the same. Although the present invention is suitable for a wide scope of applications, it is particularly suitable for preventing a contact between a plug and a lower electrode from being oxidized and for minimizing a contact resistance therein.
2. Discussion of the Related Art
As a density of semiconductor device becomes high, there has been an effort to fabricate a capacitor to keep a desired capacitance for a memory cell. One way to increase such capacitance is to utilize high dielectric materials such as Ta
2
O
5
, PZT(Pb(Zr Ti)O
3
), BST((Ba Sr))TiO
3
, or the like as a dielectric layer for a capacitor. Another way to increase the capacitance is to form a storage electrode having a stacked structure or a three-dimensional shape by using a trench in order to increase the surface area thereof.
FIG. 1
is a layout of capacitors according to the background art, and
FIG. 2
shows a cross-sectional view of capacitors along with the line II-II′ of FIG.
1
. Transistors having gate electrodes and heavily-doped impurity region
120
of sources/drains in an active region defined by a field oxide layer are fabricated in a semiconductor substrate
100
where capacitors are formed according to the background art.
Further, as shown in
FIGS. 1 and 2
, an insulating layer
102
which has a contact hole C
1
exposing the heavily-doped impurity region is formed on a semiconductor substrate
100
. A plug
104
-
1
filling the contact hole C
1
contacts the heavily-doped impurity region
120
. The plug
104
-
1
is made of a material having an excellent step coverage such as doped polysilicon, tungsten or the like. A lower electrode
106
-
1
of the capacitor is formed on the insulating layer
102
. The plug
104
-
1
is covered with the lower electrode
106
-
1
which electrically contacts the heavily-doped impurity region
120
through the plug
104
-
1
. Then, a dielectric layer
108
and an upper electrode
112
are formed on the lower electrode
106
-
1
in this order.
In
FIG. 1
, the dielectric layer
108
and the upper electrode
106
-
1
which cover the lower electrode
106
-
1
are omitted for convenience. A circled portion indicated by a dotted line shows the plug
104
-
1
covered with by the lower electrode
106
-
1
.
FIGS. 3A
to
3
C are cross-sectional views illustrating the process steps of fabricating method of capacitors according to the background art. A fabricating method of a capacitor having the aforementioned structure will be described as follows.
Initially referring to
FIG. 3A
, an insulating layer
102
is formed on a semiconductor substrate
100
having a transistor therein by depositing silicon oxide using chemical vapor deposition (CVD). A contact hole C
1
is formed by patterning the insulating layer
102
to expose a heavily-doped impurity region
120
.
A first conductive layer
104
is formed on the insulating layer
102
including the heavily-doped impurity region
120
through the contact hole C
1
. A thickness of the first conductive layer
104
is thick enough to completely fill up the contact hole C
1
. A material having an excellent step coverage, such as doped polysilicon, tungsten, or the like, may be an example for the first conductive layer
104
and formed by CVD.
Referring to
FIG. 3B
, a plug
104
-
1
electrically connected to the heavily-doped impurity region
120
is formed by etch-back the first conductive layer
104
until the top surface of the insulating layer
102
is exposed so that only a portion of the conductive layer
104
remains in the contact hole C
1
. A second conductive layer
106
(for example, platinum) is then formed on the insulating layer
102
including the plug
104
-
1
. Having a low reactivity and a desirable interfacial characteristic, platinum (Pt) is widely used for forming a lower electrode of a capacitor. Subsequently, a photoresist pattern
110
defining a lower electrode of a capacitor is formed on the second conductive layer
106
.
Referring to
FIGS. 3C
, a lower electrode
106
-
1
is formed by removing a portion of the second conductive layer
106
using the photoresist pattern
110
as a mask. After the photoresist pattern
110
is removed, a dielectric layer
108
is deposited on the insulating layer
102
including the lower electrode
106
-
1
. For instance, a high dielectric constant material
108
, such as Ta
2
O
5
, PZT(Pb(Zr Ti)O
3
), BST((Ba Sr)TiO
3
, or the like, may be used for the dielectric layer. When the dielectric layer having a high dielectric material is formed, Rapid Thermal Processing (RTP) is accompanied under oxygen atmosphere in order to prevent the dielectric layer from being metalized by substituting oxygen with carbon. A background art capacitor is completed by forming an upper electrode
112
on the dielectric layer
108
.
However, when a thermal treatment is performed on the dielectric layer in the background art, oxygen is diffused through the lower electrode due to an excessive heat, thereby oxidizing the surface of the plug in contact with the lower electrode. Consequently, a contact resistance becomes high and the capacitor may be short-circuited with the transistor.
SUMMARY OF THE INVENTION
Accordingly, the present invention is directed to a capacitor and a method of fabricating the same that substantially obviates one or more of the problems due to limitations and disadvantages of the related art.
An object of the present invention is to provide a capacitor in a semiconductor device having a low contact resistance between a plug and a lower electrode of a capacitor by forming a conductive layer between a plug and a lower electrode.
Another object of the present invention is to provide a method of fabricating a capacitor having a low contact resistance between a plug and a lower electrode of a capacitor by preventing the plug surface from being oxidized in the process of thermal treating the dielectric layer.
Additional features and advantages of the invention will be set forth in the description which follows and in part will be apparent from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention will be realized and attained by the structure particularly pointed out in the written description and claims hereof as well as the appended drawings.
To achieve these and other advantages and in accordance with the purpose of the present invention, as embodied and broadly described, a capacitor includes a semiconductor substrate, an impurity region in the semiconductor substrate, a first insulating layer on the semiconductor substrate, the first insulating layer having a first contact hole to expose the impurity region, a first conductive layer in the contact hole, a second conductive layer on the first insulating layer, a second insulating layer on the first insulating layer including the second conductive layer, the second insulating layer contacting the first portion of the second conductive layer, a lower electrode on the second insulating layer, the lower electrode being not directly contacting the first conductive layer, a dielectric layer on the lower electrode including the second insulating layer, and an upper electrode on the dielectric layer.
In another aspect of the present invention, a method of fabricating capacitor includes the steps of forming a first insulating layer on a semiconductor substrate wherein a transistor having an impurity region is formed on the semiconductor substrate and a contact hole which discloses the impurity region is formed in the first insulating layer, forming a plug filling up the contact hole, forming a first conductive layer on the first insulating layer wherein a portion of the first conductive layer corresponds to the plug and the other portion of the first conductive layer does not correspond to the plug, forming a second insulating layer on the first insulati

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