Method of bonding silver to glass and mirrors produced according

Stock material or miscellaneous articles – Composite – Of silicon containing

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156643, 156663, 427 35, 427 38, 427 541, 427167, 427294, 427309, 427314, 427399, 427404, 428450, 428469, 428480, 428701, 4289122, B32B 904

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045474320

ABSTRACT:
A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

REFERENCES:
Materials Science and Engineering, vol. 53, Maddin, pp. 1-168.
Solar Energy Materials 3, 1980, 301-316, Bieg et al.
Optics Communication, vol. 8, No. 3, 7-73, Hass et al., 183-185.
Hass et al., Applied Optics, Nov 1975, vol. 14, No. 11, 2639-2644.

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