Electrochemical polymerization of pyrroles, an anode for carryin

Chemistry: electrical and wave energy – Processes and products

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204 59R, 204 72, 204 78, 2041809, 2041802, 252500, 526 62, C25B 302

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active

045472700

ABSTRACT:
Pyrroles or mixtures of pyrroles with comonomers are polymerized electrochemically by anodic oxidation of the monomers in solution or dispersion in an electrolyte solvent, in the presence of a conductive salt, with deposition of the pyrrole polymer at the sheet-like anode, by a process in which the anode used consists of an electrically non-conductive sheet-like element which can be impregnated with the electrolyte solution and one or more electrically conducting support and contact strips which connects electrically to a current supply for the anode.
The special anode for the electrochemical polymerization of pyrroles, and the products obtainable by the process.

REFERENCES:
patent: 3574072 (1971-04-01), Louvar
patent: 4401545 (1983-08-01), Naarmann et al.
patent: 4468291 (1984-08-01), Naarmann et al.
"New Electrochemically Generated Organic Conducting Polymers", Tourillon et al, Spring MTG-Electrochemical Society Incorporated, May, 1982.
Chemical Engineers' Handbook, Perry et al, 1973, pp. 4-68 and 4-69.
Electrochemical Polymerization of Pyrrole, Diaz et al, J.C.S. Chem. Comm., 1979, p. 635.

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