Oximation process

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C24908

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053490886

ABSTRACT:
An improved process for oximation of carbonyl compounds, such as ketones and aldehydes by oximation with hydroxylamine including oximation processes carried out in the presence of a catalytic amount of an alkyl phenol phase transfer catalyst, such as nonylphenol or dodecylphenol and the presence of an alkali metal or alkaline earth metal compound. The resulting oximes are useful as metal extractants.

REFERENCES:
patent: 3449066 (1969-06-01), Swanson
patent: 3592775 (1971-07-01), Swanson
patent: 4133834 (1979-01-01), Pickens
patent: 4507268 (1985-03-01), Kordosky et al.
patent: 4868334 (1989-09-01), Mathew et al.
Mathur et al., "Laboratory Experiments on Phase-Transfer-Catalyzed Reactions of Neutral Molecules", J. Chem. Ed., 67, p. 273, Mar. 1990.

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