Catalyst composition for the preparation of ethylene from ethane

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502302, 502304, B01J 2302, B01J 2310, B01J 2326, B01J 2334

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active

051127938

ABSTRACT:
Solid solution catalyst in particulate form consisting of attrition resistant .alpha.-Al.sub.2 O.sub.3 particles with 0.5 to 10% by weight, expressed as the oxide, of iron cations substituted for aluminum cations in said catalyst support stabilized with 0.5 to 10% by weight, expressed as the oxide, of lanthanum and modified with at least two, preferably three, metal cations selected from the metals consisting of chromium, cobalt, magnesium, manganese, and barium; wherein one of said metal cations is barium and said catalyst has X-ray diffraction pattern with peak positions different than that of the .alpha.-Al.sub.2 O.sub.3 structure. A process is disclosed which produces ethylene from ethane while producing reduced amounts of vinyl chloride from said ethane to ethylene process.

REFERENCES:
patent: 3420901 (1969-01-01), Schulz
patent: 4100211 (1978-07-01), Magistro
patent: 4102936 (1978-07-01), Magistro
patent: 4119570 (1978-10-01), Kroenke et al.
patent: 4158645 (1979-06-01), Magistro

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