Reductive alkylation and dehalogenation of m-nitrobenzyl halides

Details Reductive alkylation and dehalogenation of m-nitrobenzyl halides Reductive alkylation and dehalogenation of m-nitrobenzyl halides

1979-07-05

1981-08-04

Hines, Robert V.

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

564406, 564412, C07C 8508, C07C 8524

Patent

active

042823803

ABSTRACT:
Substituted N-alkylated aromatic amines are produced by reductively alkylating and dehalogenating the corresponding m-nitrobenzyl halides with pressurized hydrogen in the presence of a ketone and a platinum catalyst.

REFERENCES:
patent: 3350450 (1967-10-01), Dorell et al.
patent: 3541153 (1970-11-01), Sandridge
patent: 3933739 (1976-01-01), Wilder
patent: 4078001 (1978-03-01), Sommers
patent: 4085141 (1978-04-01), Wedemeyer et al.
patent: 4140718 (1979-02-01), Symon
Sobolev et al. "Chemical Abstracts", vol. 54, p. 411b (1960).
Berezovskii et al."Chemical Abstracts", vol. 54, p. 8679e (1960).

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