Process for metalating halogenated polyolefins

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525366, G08F 842

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045943958

ABSTRACT:
A process for metalating a halogenated polyolefin so that only a very low percentage of the halogen originally present in the halogenated polyolefin is actually reacted during the process. The process comprises adding a solvated transmetalating organometallic compound to a cement mix of a halogenated polyolefin and a solvent. The transmetalating organometallic compound is present in the reaction in a molar amount less than the molar amount of the halogen content of the halogenated polyolefin. The reaction temperature is below 0.degree. C.

REFERENCES:
patent: 3887533 (1975-06-01), Mukerjee
patent: 3978161 (1976-08-01), Nielsen et al.
"Chemical Conversions of Halogenated Polyolefines Caused by Organo-Lithium Compounds":, N. A. Plate et al., Vysokomol. soyed. 8: No. 9, pp. 1562-1567, (1966).
"The Role of Chemico-Structural Effects in the Modification of Polymers", N. A. Plate, Vysokomol. soyed. A10: No. 12, pp. 2650-2661 (1968).
"Chemical Transformations and Catalytic Activity of Macromolecular Polylithium Compounds Polymerization", N. A. Plate et al., J. Polymer Sci.: Part C, No. 22, pp. 547-568, (1969).

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