Plant protecting and regulating compositions – Antidotes – Hetero ring containing antidote
Patent
1994-02-04
1996-02-13
Raymond, Richard L.
Plant protecting and regulating compositions
Antidotes
Hetero ring containing antidote
504105, 504106, 504108, A01N 2532, A01N 4312
Patent
active
054911230
DESCRIPTION:
BRIEF SUMMARY
The present invention relates to herbicides containing one or more antagonistic 3-aminobenzo[b]thiophenes of the general formula I ##STR2## where
R.sup.1 is --COX or --COOX,
X is hydrogen, halogen, amino which may be unsubstituted or may carry from one to three substituents selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, hydroxy-C.sub.1 -C.sub.4 -alkyl, phenyl and benzyl substituents, C.sub.1 -C.sub.10 -alkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.3 -C.sub.10 -cycloalkenyl, where the four last-mentioned groups may be unsubstituted or partially or completely halogenated and the four last-mentioned groups may furthermore contain one or two further carboxyl or carbonyl groups, a 5-membered or 6-membered aromatic heterocyclic structure having one oxygen and one sulfur atom or having from 1 to 3 hetero atoms selected from the group consisting of from 1 to 3 nitrogen atoms and one oxygen or sulfur atom, and all three hetero atoms may not be adjacent to one another at the same time, phenyl or naphthyl, where these groups may carry from one to three substituents selected from the group consisting of halogen, --COY and --COOY, and these groups may additionally carry a number of halogen atoms corresponding to the number of substitutable carbon atoms present;
Y is C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl or phenyl;
R.sup.2 and R.sup.3 are each hydrogen, cyano, nitro, halogen, mercapto, amino whose nitrogen atom may carry from one to three substituents selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, hydroxy-C.sub.1 -C.sub.4 -alkyl, phenyl and benzyl substituents, C.sub.1 -C.sub.10 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.2 -C.sub.8 -alkenyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.3 -C.sub.10 -cycloalkenyl, where the four last-mentioned groups may be partially or completely halogenated, phenyl or naphthyl, a 5-membered or 6-membered aromatic heterocyclic structure having one oxygen and one sulfur atom or having from one to three hetero atoms selected from the group consisting of three nitrogen atoms and one oxygen or sulfur atom, where in the case of three hetero atoms all may not be adjacent to one another at the same time;
R.sup.4 to R.sup.7 are each hydrogen, phenyl, naphthyl or a 5-membered or 6-membered aromatic heterocyclic structure having one oxygen and one sulfur atom or having from one to three hetero atoms selected from the group consisting of three nitrogen atoms and one oxygen or sulfur atom, where in the case of three hetero atoms all may not be adjacent to one another at the same time and where the aromatic and heteroaromatic groups may furthermore carry from one to three substituents selected from the group consisting of halogen, --COY and --COOY, and these groups may additionally carry a number of halogen atoms corresponding to the number of substitutable carbon atoms present, C.sub.1 -C.sub.10 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.3 -C.sub.10 -cycloalkenyl; or R.sup.4 and R.sup.5 and/or R.sup.6 and R.sup.7, together with the nitrogen atom to which they are bonded, form a 5-membered to 7-membered ring, and the basic salts of the compounds I which carry one or more carboxyl, hydroxythiocarbonyl or sulfo groups and the acidic salts of compound I which contain a basic nitrogen atom, and one or more herbicidal active ingredients selected from
A) the group consisting of the cyclohexenone derivatives of the general formula II ##STR3## where
R.sup.a is C.sub.1 -C.sub.6 -alkyl;
R.sup.b is hydrogen, one equivalent of an agriculturally useful cation, C.sub.2 -C.sub.8 -alkylcarbonyloxy, C.sub.1 -C.sub.10 -alkylsulfonyl, C.sub.1 -C.sub.10 -alkylphosphonyl or benzoyl, benzenesulfonyl or benzenephosphonyl, where the three last-mentioned groups may furthermore each carry from one to five halogen atoms;
R.sup.c is hydrogen, cyano, formyl, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, phenoxy-C.sub.1 -C.sub.6 -alkyl, phenylthio-C.su
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Hagen Helmut
Landes Andreas
Nilz Gerhard
Roetsch Thomas
Walter Helmut
BASF - Aktiengesellschaft
Bembenick Brian
Raymond Richard L.
LandOfFree
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