Cyclopropylamines containing trifluoromethyl groups

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C 8734

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047743581

ABSTRACT:
A cyclopropylamine of the formula ##STR1## and a process for producing the same by reacting a cyclopropylcarboxylic acid amine of the formula ##STR2## with sulphur tetrafluoride in anhydrous hydrogen fluoride. The cyclopropylamine is useful in the preparation of benzoic acid amides which have an insecticidal action.

REFERENCES:
patent: 4668830 (1987-05-01), Desbois
patent: 4705788 (1987-11-01), Schriewer et al.
Chemical Abstracts published by the American Chemical Society, vol. 88, Jun. 12-Jun. 26 (Abstracts 170497-202625), 1978, P 1537, p. 1; 1-Pharmacodynamics; p. 702, 24-Alicyclic Compounds.
The Journal of Organic Chemistry, vol. 27; Jan.-Apr. 1962, pp. 1-1492), The Chemistry of Sulfur Tetrafluoride. IX Reaction with Amino Acids in Hydrogen Fluoride.sup.1, pp. 1406`1409.
Journal of Organic Chemistry, 27, 1406 (1962).
J. Chem. Soc., 2119-2132 (1960).
Synthesis, 46 (1978).
Coll. Czech. Chem. Comm., 47, 2291-2305 (1982).

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