Water-splitting cycle with graphite intercalation compounds

Chemistry of inorganic compounds – Hydrogen or compound thereof – Elemental hydrogen

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423579, 423448, 252503, 252508, C01B 302, C01B 1318, C01B 3104

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046631445

ABSTRACT:
Water is decomposed to molecular hydrogen and molecular oxygen in a thermochemical cycle which comprises (i) reacting Cl.sub.2, Br.sub.2 or BrCl with water to obtain oxygen and hydrogen halide; (ii) forming a graphite intercalation compound with a hydrogen halide from step (i) and a metal halide selected from MBr.sub.i Cl.sub.3-i, wherein M is aluminum, gallium or indium and i is 0, 1, 2 or 3, and thereby obtaining hydrogen; (iii) decomposing by heating the graphite intercalation compound formed in step (ii); (iv) recycling the halogen produced in step (iii) for use in step (i); and (v) recycling the metal halide and graphite produced in step (iv) for use in step (ii).

REFERENCES:
patent: 3409563 (1968-11-01), Olstowski
patent: 3976714 (1976-08-01), Rodewald
patent: 3984352 (1976-10-01), Rodewald
patent: 4080436 (1978-03-01), Fremery et al.
patent: 4089938 (1978-05-01), Turner
patent: 4102937 (1978-07-01), Harris
patent: 4271045 (1981-06-01), Steigerwald et al.
K. Leong and W. C. Forsman, "Electron Transfer to Protons in Graphite Intercalation," Synthetic Metals 6, 61-63 (1983).

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